Aluminium sulfate
From Wikipedia, the free encyclopedia
| Aluminium sulfate | |
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| IUPAC name | Aluminium sulfate hexadecahydrate |
| Other names | Cake alum Filter alum Papermaker's alum alunogenite Aluminum sulfate Aluminium sulphate |
| Identifiers | |
| CAS number | [10043-01-3] |
| EINECS number | |
| RTECS number | BD1700000 |
| Properties | |
| Molecular formula | Al2(SO4)3·16H2O |
| Molar mass | 342.15 g/mol as anhydrous salt |
| Appearance | white crystalline solid |
| Density | 2.672 g/cm³, solid |
| Melting point |
770 °C decomp. |
| Solubility in water | 870 g/L |
| Structure | |
| Crystal structure | monoclinic (hydrate) |
| Related compounds | |
| Other cations | Gallium sulfate Magnesium sulfate |
| Related compounds | See Alum |
| Supplementary data page | |
| Structure and properties |
n, εr, etc. |
| Thermodynamic data |
Phase behaviour Solid, liquid, gas |
| Spectral data | UV, IR, NMR, MS |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox disclaimer and references |
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Aluminium sulfate, written as Al2(SO4)3 or Al2O12S3, is a widely used industrial chemical. It is sometimes incorrectly referred to as alum, as it is closely related to this group of compounds. It occurs naturally as the mineral alunogenite. It is frequently used as a flocculating agent in the purification of drinking water[1][2] and waste water treatment plants, and also in paper manufacturing.
Aluminium sulfate is rarely, if ever, encountered as the anhydrous salt. It forms a number of different hydrates, of which the hexadecahydrate Al2(SO4)3•16H2O and octadecahydrate Al2(SO4)3•18H2O are the most common.
It can also be very effective as a molluscicide, killing spanish slugs. [1]
Contents |
[edit] Preparation
Aluminium sulfate may be made by dissolving aluminium hydroxide, Al(OH)3, in sulfuric acid, H2SO4:
- 2 Al(OH)3 + 3 H2SO4 + 3 H2O → Al2(SO4)3·6H2O
[edit] Uses
Aluminium Sulfate is used in water purification and as a mordant in dyeing and printing textiles. In water purification, it causes impurities to coagulate which are removed as the particulate settles to the bottom of the container or more easily filtered. This process is called coagulation or flocculation.
When dissolved in a large amount of neutral or slightly-alkaline water, aluminium sulfate produces a gelatinous precipitate of aluminium hydroxide, Al(OH)3. In dyeing and printing cloth, the gelatinous precipitate helps the dye adhere to the clothing fibers by rendering the pigment insoluble.
Aluminium sulfate is sometimes used to reduce the pH of garden soil, as it hydrolyzes to form the aluminium hydroxide precipitate and a dilute sulfuric acid solution.
Aluminium sulfate is the active ingredient of some antiperspirants; however, beginning in 2005 the US Food and Drug Administration no longer recognized it as a wetness reducer.
Aluminium sulfate is usually found in baking powder, where there is controversy over its use due to concern regarding the safety of adding aluminum to the diet.
In construction industry it is used as waterproofing agent and accelerator in concrete. Another use is a foaming agent in fire fighting foam.
It is also used in styptic pencils, and pain relief from stings and bites; it is the active ingredient in popular pain relief products such as Stingose.
[edit] See also
[edit] References
- ^ Global Health and Education Foundation (2007). Conventional Coagulation-Flocculation-Sedimentation. Safe Drinking Water is Essential. National Academy of Sciences. Retrieved on 2007-12-01.
- ^ Kvech S, Edwards M (2002). "Solubility controls on aluminum in drinking water at relatively low and high pH". WATER RESEARCH 36 (17): 4356–4368. doi:. PMID 12420940.
- Pauling, Linus (1970). General Chemistry. W.H. Freeman: San Francisco. ISBN 0-486-65622-5.
