2,3-Dihydropyran
From Wikipedia, the free encyclopedia
| 2,3-Dihydropyran | |
|---|---|
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| IUPAC name | 3,4-Dihydro-2H-pyran |
| Other names | Dihydropyran |
| Identifiers | |
| CAS number | [110-87-2] |
| PubChem | |
| Properties | |
| Molecular formula | C5H8O |
| Molar mass | 84.12 |
| Appearance | colorless liquid |
| Density | 0.992 g/mL at 25 °C |
| Melting point |
-70 °C, 203 K, -94 °F |
| Boiling point |
86 °C, 359 K, 187 °F |
| Solubility in water | organic solvents |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox disclaimer and references |
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2,3-Dihydropyran is the organic compound with the formula C5H8O. This cyclic ether is used to protect alcohols in organic synthesis. Dihydropyran is prepared by the dehydration of tetrahydrofurfuryl alcohol over alumina at 300-400 °C.[1]
Dihydropyran reacts with alcohols to form tetrahydropyranyl ethers. These ethers resist a variety of reactions, and the THP group can be removed with aqueous acid.
[edit] References
- ^ R. L. Sawyer and D. W. Andrus “2,3-Dihydropyran” Organic Syntheses, Coll. Vol. 3, p.276 (1955). http://www.orgsyn.org/orgsyn/pdfs/CV3P0276.pdf.
