Xenon tetrafluoride

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Xenon tetrafluoride
XeF4 crystals. 1962.
General
Systematic name Xenon tetrafluoride
Other names  ?
Molecular formula XeF4
SMILES  ?
Molar mass 207.2836 g/mol
Appearance White solid
CAS number [13709-61-0]
Properties
Density and phase 4.040 g/cm3, ?
Solubility in water  ? g/100 ml (?°C)
Melting point  ? °C (? K)
Boiling point 117°C (390 K)
Acidity (pKa)  ?
Basicity (pKb)  ?
Chiral rotation [α]D  ?°
Viscosity  ? cP at ?°C
Structure
Molecular shape Octahedral
Coordination
geometry
Square Planar
Crystal structure  ?
Dipole moment None D
Hazards
MSDS External MSDS
Main hazards  ?
NFPA 704
Flash point  ?°C
R/S statement R: ?
S: ?
RTECS number  ?
Supplementary data page
Structure and
properties
n, εr, etc.
Thermodynamic
data
Phase behaviour
Solid, liquid, gas
Spectral data UV, IR, NMR, MS
Related compounds
Other anions  ?
Other cations  ?
Related ?  ?
Related compounds  ?
Except where noted otherwise, data are given for
materials in their standard state (at 25°C, 100 kPa)
Infobox disclaimer and references

Xenon tetrafluoride, XeF4, is one of the few chemical compounds involving a noble gas. It was the first discovered binary compound containing a noble gas. It is formed by the reaction of Xe and F2 in the ratio of 1 mol Xe to 2 mol F2. The process is exothermic, releasing 251kJ per mol of Xe. It occurs as colorless crystals.

It sublimes at 115.7 °C (240.26 °F).

Xenon fluorides are all exergonic, and quite stable at normal temperatures. They do react readily with water, even pulling water from air, so they must be kept in anhydrous conditions.

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