Trifluoromethylisocyanide

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Trifluoromethylisocyanide

Trifluoromethylisocyanide

Systematic (IUPAC) name
Trifluoro-methyl-azaniumylidyne methane
Identifiers
CAS number 105879-13-8
PubChem         145434
Chemical data
Formula C2NF3 
Mol. weight 95.023
SMILES [C-]#[N+]C(F)(F)F
Complete data

Trifluoromethylisocyanide is the chemical compound with the formula CF3NC. It is a isocyanide and a fluorocarbon. Polymerisation occurs even at temperatures below its boiling point of -80°C. As a ligand in coordination chemistry, this species behaves similarly to carbon_monoxide.[1]

The compound trifluoracetonitrile (CF3CN) is an isomer to trifluoromethylisocyanide. The nitrile is more stable, as is the usual case.

[edit] References

  1. ^ D. Lentz (1994). "Fluorinated Isocyanides - More than Ligands with Unusual Properties". Angewandte Chemie International. Edition English 33: 1315-1331. DOI:10.1002/anie.199413151. 

[edit] External links