Pyrophosphoric acid

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Pyrophosphoric acid
Chemical structure of pyrophosphoric acid
3D model of pyrophosphoric acid
General
Systematic name phosphonooxyphosphonic
acid
Other names diphosphoric acid
Chemical formula H4P2O7
SMILES OP(=O)(O)OP(=O)(O)O
Molecular mass 177.98 g/mol
CAS number 2466-09-3
Properties
Density  ? g/cm³
Melting point 61 °C
Boiling point  ? °C
Dissociation
constants
Ka1 = 3 × 10-2
Ka2 = 4.4 × 10-3
Ka3 = 2.5 × 10-7
Ka4 = 5.6 × 10-10
Except where noted otherwise, data are given for
materials in their standard state (at 25 °C, 100 kPa)
Infobox disclaimer and references

Pyrophosphoric acid, also known under the name diphosphoric acid, is a syrupy liquid or a needle-like crystalline solid. Pyrophosphoric acid is colorless, odorless, hygroscopic and is soluble in water, diethyl ether, and ethyl alcohol. It is the anhydride of phosphoric acid and is produced from phosphoric acid by dehydration. Pyrophosphoric acid slowly hydrolyzes in the presence of water into phosphoric acid.

2H3PO4 ⇌ H4P2O7 + H2O

Pyrophosphoric acid is a medium strong inorganic acid. The anion, the salts, and the esters of pyrophosphoric acid are called pyrophosphates.

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