Talk:NMR spectroscopy
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[edit] Image Removal
I removed this image because there's some unsafe lab practice in the picture and wikipedia should not be encouraging bad safety. User should be wearing gloves while handling unlabeled compound in a marginally sealed tube. --Takometer 01:58, 23 April 2006 (UTC)
- It's not unlabelled. Look at the top. Safe lab practice doesn't demand you to wear gloves regardless of what you are doing. In this case it was a harmless protein sample in water. I put the picture back in, since I think it adds to the information content of the article. Kjaergaard 02:09, 23 April 2006 (UTC)
- Usually I'd agree with Takometer that chem photos should be seen to be safe, but I think it's appropriate in this case not to have gloves. In fact, gloves are usually discouraged with NMR tubes as they can lead to contamination of the probe. Walkerma 04:25, 23 April 2006 (UTC)
[edit] History
Page moved from NMR_Spectroscopy (now a redirect). Lee-Jon 09:28, 19 May 2005 (UTC).
Added spin-spin (scalar) coupling section. Lee-Jon 10:45, 19 May 2005 (UTC)
[edit] Work in Progress!
Hello all! This page has been created at a request on the NMR discussion board. The idea for this page is to give a simple introduction into NMR_Spectroscopy without the need for theory. The knowledge typically required of a graduate student to understand his NMR spectra!
It has been written in a basic style and contains simple examples. I ask people who'd like to edit in more detail/or more complex terms, to refer and preferably reference to the Nuclear_magnetic_resonance page. Lee-Jon 10:45, 19 May 2005 (UTC)
[edit] Are you finished?
User:Lee-Jon, are you finished with this NMR Spectroscopy article? If you are, I might make more edits to it. If not, I would rather wait until you are finished. H Padleckas 19:33, 23 May 2005 (UTC)
[edit] Hi!
I'm still working on some sections. I'll post when I'm done. What were you thinking of adding? -Lee-Jon
- I have just written an article discussing tetramethylsilane, often called TMS. H Padleckas 07:36, 27 May 2005 (UTC)
[edit] Protein NMR
I added a section a section on protein NMR, even though I'm not sure it fits very well with the rest. Eventually it is going to get it's own page.... Kjaergaard 06:40, 3 January 2006 (UTC)
[edit] Peak sizes in split peaks, style
I just noticed this phrase in the section on multiplicity: "The ratio of height between them is 1:2:1." Shouldn't that be the ratio of areas? With the doublet it uses the word area, though for quartets it says "intensity" which seems rather vague to me. Isn't the word area or areas the correct term here? Walkerma 05:37, 3 February 2006 (UTC)
- By first principles, area would be right--"intensity" as "strength of signal" where the "signal" is the whole peak. By practical experience, height is not reliable. OTOH, I've seen it taught as height because it's aproximately proportional to area for reasonably isolated signals in simple compounds (i.e., classroom examples). Integration curves are often hard to read for the level of accuracy needed to see the ratios and the various peaks of a multiplets often overlap. In fact, the deviation from a symmetric height ratio at one chemical shift is taught as a way to figure out what other chemical shift might be coupled to it. DMacks 06:01, 3 February 2006 (UTC)
Also, I notice that the style in this section is more like that of a tutoring session than an encyclopedia, complete with questions like "So do we get four peaks?" The content looks good (other than the area/height problem), but shouldn't it be more encyclopedic? I'll await comments before making any changes. Walkerma 05:37, 3 February 2006 (UTC)
[edit] examples
It would be nice to see some picture examples of NMR spectra, as by reading the article, it is hard to get a grasp of what the specta look like Jhum101 06:11, 25 February 2006 (UTC)
[edit] Ethanol Spectum?
Does anyone have an ethanol NMR spectrum similar to the one described in the article? Since interpreting NMR spectra for structure determination is a very visual process, it might be useful to have a graphic to go along with the description of chemical shift, integration, and spin-spin coupling in order to make it more clear. Ghiles 11:30, 16 May 2006 (UTC) It should be fairly easy to make a sketch of one, that outlines the main features... I'll look at it when I have time.... Kjaergaard 16:10, 16 May 2006 (UTC)
[edit] Virtual Coupling
Can anyone explain virtual coupling? I am unclear as to the term and I think a good explanation would be useful. Not sure if it should be its own topic or under NMR spectroscopy. Nothing found through a wiki search. M_Stone 16:51, 12 June 2006
- I'm not sure that would be appropriate for a general article on interpreting NMR, but perhaps in an article on interpreting couplings in an NMR spectrum which certainly is a topic that might deserve its own article. Maybe I'll gather some source material together and try to write one up soon. Ghiles 10:16, 16 June 2006 (UTC)
- I agree. Good Idea. M_Stone 17:42, 16 June 2006
[edit] Redirects from other articles
I think that MRS is another generally accepted common term for NMR spectroscopy. Thus, the MRS disambiguation page should have a reference to this page. Also, "Magnetic Resonance Spectroscopy" redirects to the MRI page even though it should redirect here. Also, the MRS section of the MRI should have a link to here because this is really the main article to the small description over there.
[edit] Chemical shift
Can someone explain the chemical shifts in molecules like flouroethane,chloroethane,bromoethane....???
[edit] Deuterated solvents list
I wonder if we really need the list, bearing in mind that CDCl3 is just a stub, while the other articles are redlinked. The bulk properties are not very much different than the undeuterated form, and probably will only remain a stub permanently. There are also important solvents not listed such as DMSO-d6 and D2O. --Rifleman 82 15:00, 1 February 2007 (UTC)
- Hmm .. right. Err .. what about a document 'deuterated solvents', that describes how they are made, that their properties are closely related to the un-deuterated solvents, something about specific toxicity and some special properties (I think there are cases of odd effects on boiling points). And then create a redirect from the common deuterated NMR-solvents to these articles? --Dirk Beetstra T C 15:10, 1 February 2007 (UTC)
- No objections, though I won't be able to contribute much to this article. I assume this would be a logical daughter article of Nuclear Magnetic Resonance, similar to NMR tube? --Rifleman 82 16:25, 1 February 2007 (UTC)
[edit] NMR Data Processing
I have proposed that the NMR Data Processing page is being merged into this page. I don't know if there is anything worth salvaging over there, but the page doesn't make much sense by it self.... Kjaergaard 21:58, 13 February 2007 (UTC)
