Magnesium oxide

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Properties
Image:Magnesium oxide crystals (1350x).jpg
Magnesium oxide crystals - SEM image (1350x)

General

Name Magnesium oxide
Chemical formula MgO
Common Reaction 2Mg + O2 ---> 2MgO
Appearance White, powdery, iron

Physical

Formula weight 40.3044 g/mol
Melting point 3073 K (2800 °C)
Boiling point 3873 K (3600 °C)
Density 3.58 kg/dm3
Crystal structure Cubic FCC
Solubility 0.00062 g in 100 g water

Thermochemistry

ΔfH0liquid  ? kJ/mol
ΔfH0solid -601 kJ/mol
S0solid 32.51 J/(mol·K)

Misc.

Thermal conductivity 42 W m-1 K-1 at 0 °C
Coefficient of thermal expansion[1] 9.84 ×10-6/K at 0 °C
Specific heat capacity 877 J kg-1 K-1
Dielectric constant 9.65 at 1 MHz
Young's modulus 250 GPa
Shear Modulus 155 GPa
Bulk modulus 155 GPa
Poisson's ratio 0.18

Safety

Ingestion Used as an antacid and/or a laxative. Available over-the-counter.
Inhalation Causes irritation of upper respiratory tract.
Skin Causes irritation.
Eyes Causes irritation.

SI units were used where possible. Unless otherwise stated, standard conditions were used.

Disclaimer and references

Magnesium oxide
Magnesium oxide

Magnesium oxide, or magnesia, is a white solid mineral that occurs naturally as periclase and is a source of magnesium. See also oxide. It has an empirical formula of MgO. It is formed by an ionic bond between one magnesium and one oxygen atom.

Contents

[edit] Applications

It is used by many libraries for preserving/deacidifying books, and as an insulator in industrial cables. It is also used as a medication to relieve heartburn, sour stomach, or acid indigestion. Medical uses of magnesium oxide also include using it as a short-term laxative, or used to supplement a diet with magnesium.

Magnesium oxide is used as a basic refractory material for lining crucibles.

Magnesium oxide is a principal ingredient in construction materials used for fireproofing.

It is used as a reference white colour in colorimetry. The emissivity value is about 0.9

Pressed MgO is used as an optical material. It is transparent from 300 nm to 7 µm. The refractive index is 1.72 at 1 µm. It is sometimes known by the Eastman Kodak trademarked name Irtran-5, although this designation is long since obsolete. Crystalline pure MgO is available commercially and has small use in infra-red optics.

Magnesium oxide (electrical grade) is used extensively in electrical heating industry. There are several mesh sizes available and most commonly used ones are 40 and 80 mesh per the American Foundry Society. The extensive use is due to its high di-electric strength and average thermal conductivity. MgO is usually crushed and compacted with minimal airgaps or voids. The electrical heating industry also experimented with Aluminium oxide but is not used now.

Magnesium oxide is also used in animal feeding industry and there are special grades available. MgO is hygroscopic in nature and care must be taken to protect it from moisture. Magnesium hydroxide (Mg(OH)2) which forms in the presence of water can be reversed by heating to separate moisture.

[edit] Precautions

Inhalation of magnesium oxide fumes can cause metal fume fever.

[edit] See also

Related materials calcium oxide, barium oxide, Magnesium sulfide.

[edit] References

  1. ^ G. K White, J. Phys D, 1973, 6, 2070

[edit] External links

[edit] Suppliers