Magnesium oxide
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Image:Magnesium oxide crystals (1350x).jpg |
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General |
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Name | Magnesium oxide |
Chemical formula | MgO |
Common Reaction | 2Mg + O2 ---> 2MgO |
Appearance | White, powdery, iron |
Physical |
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Formula weight | 40.3044 g/mol |
Melting point | 3073 K (2800 °C) |
Boiling point | 3873 K (3600 °C) |
Density | 3.58 kg/dm3 |
Crystal structure | Cubic FCC |
Solubility | 0.00062 g in 100 g water |
Thermochemistry |
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ΔfH0liquid | ? kJ/mol |
ΔfH0solid | -601 kJ/mol |
S0solid | 32.51 J/(mol·K) |
Misc. |
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Thermal conductivity | 42 W m-1 K-1 at 0 °C |
Coefficient of thermal expansion[1] | 9.84 ×10-6/K at 0 °C |
Specific heat capacity | 877 J kg-1 K-1 |
Dielectric constant | 9.65 at 1 MHz |
Young's modulus | 250 GPa |
Shear Modulus | 155 GPa |
Bulk modulus | 155 GPa |
Poisson's ratio | 0.18 |
Safety |
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Ingestion | Used as an antacid and/or a laxative. Available over-the-counter. |
Inhalation | Causes irritation of upper respiratory tract. |
Skin | Causes irritation. |
Eyes | Causes irritation. |
SI units were used where possible. Unless otherwise stated, standard conditions were used. |
Magnesium oxide, or magnesia, is a white solid mineral that occurs naturally as periclase and is a source of magnesium. See also oxide. It has an empirical formula of MgO. It is formed by an ionic bond between one magnesium and one oxygen atom.
Contents |
[edit] Applications
It is used by many libraries for preserving/deacidifying books, and as an insulator in industrial cables. It is also used as a medication to relieve heartburn, sour stomach, or acid indigestion. Medical uses of magnesium oxide also include using it as a short-term laxative, or used to supplement a diet with magnesium.
Magnesium oxide is used as a basic refractory material for lining crucibles.
Magnesium oxide is a principal ingredient in construction materials used for fireproofing.
It is used as a reference white colour in colorimetry. The emissivity value is about 0.9
Pressed MgO is used as an optical material. It is transparent from 300 nm to 7 µm. The refractive index is 1.72 at 1 µm. It is sometimes known by the Eastman Kodak trademarked name Irtran-5, although this designation is long since obsolete. Crystalline pure MgO is available commercially and has small use in infra-red optics.
Magnesium oxide (electrical grade) is used extensively in electrical heating industry. There are several mesh sizes available and most commonly used ones are 40 and 80 mesh per the American Foundry Society. The extensive use is due to its high di-electric strength and average thermal conductivity. MgO is usually crushed and compacted with minimal airgaps or voids. The electrical heating industry also experimented with Aluminium oxide but is not used now.
Magnesium oxide is also used in animal feeding industry and there are special grades available. MgO is hygroscopic in nature and care must be taken to protect it from moisture. Magnesium hydroxide (Mg(OH)2) which forms in the presence of water can be reversed by heating to separate moisture.
[edit] Precautions
Inhalation of magnesium oxide fumes can cause metal fume fever.
[edit] See also
Related materials calcium oxide, barium oxide, Magnesium sulfide.
[edit] References
- ^ G. K White, J. Phys D, 1973, 6, 2070
[edit] External links
- National Pollutant Inventory - Magnesium Oxide Fume Fact Sheet
- NIH medicinal use
- Data page at UCL
- Ceramic data page at NIST
- Emissivity
[edit] Suppliers
- Harrick Scientific products
- Lorad chemical - as an optical coating material
- Morgan Advanced Ceramics
- Premier Chemicals LLC