- Steve Allen - writer, comedian, musician
- Adam Archuleta - NFL player
- Sal Bando - former MLB player
- Bruce Blakeman- New York Politician, Lawyer,Power Broker,Commentator (class of 1980)
- Barry Bonds - MLB player
- Amanda Borden - 1996 Summer Olympics team gold medal winner in gymnastics
- Amanda Brown - author of Legally Blonde
- William P. Carey - founder and chairman of W. P. Carey & Co. LLC
- Henry Carr - winner of two gold medals at the 1964 Summer Olympics
- Paul Casey - professional golfer
- Christopher J. Cohan - founder, Sonic Communications; owner, Golden State Warriors
- Eric Crown - chairman of the board and co-founder, Insight Enterprises
- Troy Dalbey - winner of 2 gold medals at the 1988 Summer Olympics in swimming
- Ed Dee - author
- Doug Ducey - president and CEO of Cold Stone Creamery
- Ike Diogu - NBA player
- Mike Esposito - Major League Baseball pitcher for the Colorado Rockies.
- Andre Ethier - outfielder with the Los Angeles Dodgers of MLB.
- David Fulcher - former National Football League defensive back
- Ira A. Fulton - businessman, founder of Fulton Homes
- Larry Gura - former All-Star MLB pitcher, played for the Chicago Cubs, New York Yankees, and Kansas City Royals.
- James Hartig - Peaceworker and Pioneer. More properly a graduate of the Tempe Normal School, 1891. Acted as a mediary during the amalgation of the "Hayden Ferry" and "San Pablo" settlements.
- Todd Heap - NFL player
- Cecil Heftel - founder Heftel Broadcasting; former U.S. Representative
- James Herndon - media psychologist
- Doug Hopkins - former lead guitarist and principal songwriter, Gin Blossoms
- Eddie House - NBA player
- Reggie Jackson - former MLB player, member of the Baseball Hall of Fame
- Paul Justin - retired National Football League quarterback
- Jimmy Kimmel - talk-show host and comedian
- Ian Kinsler - major league baseball player (attended)
- Bill Leen - bass player, Gin Blossoms
- Paul Lo Duca - MLB catcher for the New York Mets
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- Billy Mayfair - professional golfer
- Al Michaels - television broadcaster
- Phil Mickelson - professional golfer
- Harry Mitchell - U.S. Congressman, former Mayor of Tempe, former state Senator
- Jim Palmer - former MLB player, member of the Baseball Hall of Fame, significant Sigma Chi
- Ed Pastor - U.S. Congressman
- Scott Peterson- Criminal sentenced to death for the murder of his wife and unborn child.
- Ken Phelps - radio broadcaster, former MLB player
- Jake Plummer - NFL player
- Tom Purtzer - professional golfer
- Michael Reagan - Son of former U.S. President Ronald Reagan
- Robert Rey - plastic surgeon, television personality (Dr. 90210)
- Gerald Riggs - Former NFL running back
- Patt Rooney - retired Major League Baseball player
- b royalty - (aka Elizabeth Tom) artist [[1]]
- Brenna Sakas - Miss Arizona USA 2006
- Matt Salmon - former U.S. Congressman and gubernatorial candidate for Arizona
- Byron Scott - head coach, New Orleans Hornets; former NBA player
- Jimmy Siemers - professional water skier/ 2-time world champion
- David Spade - comedian,
- Kevin P. Brennan - President, Select Cigars inc.; Proprietor, Brenann's and The Maryland House, St. Louis, MO; Inventor, OPP (Orgasmic Prolongation Potion)
- Kate Spade - fashion designer
- Paul Spudis - geologist and lunar scientist
- Phillippi Sparks - former NFL player, member Sigma Chi
- Brenda Strong - actress
- Terrell Suggs - NFL player
- Pat Tillman - former NFL player; US Army Corporal
- Andrew Walter - NFL player
- Fee Waybill - Performer, Lead Singer of The Tubes (band)
- Danny White - College Football Hall of Fame member, former NFL quarterback, and former Arizona Rattlers coach
- Darren Woodson - former NFL player, ESPN Analyst
- Robert Z'Dar - actor
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