Iron(II) sulfide

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Iron(II) sulfide
Systematic name Iron(II) sulfide
Other names Iron sulfide,
Iron sulphide,
Iron(II) sulphide
Molecular formula FeS
Molar mass 87.911 g/mol
Density 4.84 g/cm3
Solubility (water) insoluble
Melting point 1194 °C
Boiling point xx.x °C
Appearance black solid
CAS number [xx-xx-xx]
Disclaimer and references

Iron(II) sulfide is a chemical compound with the formula FeS. In practice, iron sulfides are often non-stoichiometric. Powdered iron sulfide is pyrophoric.

FeS can be obtained by reacting iron and sulfur.

S8 (s) + 8Fe (s) → 8FeS(s)

Contents

[edit] Forms of "iron sulfide"

"Iron sulfide" exists in several distinct forms which differ in the stoichiometry and properties:

  • Pyrrhotite, Fe1-xS, a mineral as well as the waste product of the Desulfovibrio bacteria, pyrrhotite displays ferrimagnetism.
  • Troilite, FeS, which has similar material to pyrrhotite, but does not possess ferromagnetic properties.
  • Mackinawite - Fe1+xS - the least stable from of iron sulfide, mackinawite has a layered structure.

[edit] Pedagogical uses

Certain chemical principles are nicely illustrated using the chemistry of iron sulfides. The methods of chemical composition can be shown by the production of iron(II) sulfide from iron and sulfur (se equation above).

FeS(s) + 2HCl(aq) → FeCl2 (aq) + H2S(g)

[edit] See also

[edit] References

  • D. Vaughan, J. Craig, (1978) Mineral Chemistry of Metal Sulfides, Cambridge University Press. ISBN 0-521-21489-0
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