Indium(III) phosphide

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Indium(III) phosphide
Image:Indium(III) phosphide.jpg
General
Systematic name Indium phosphide
Other names Indium(III) phosphide
Molecular formula InP
Molar mass 145.792 g/mol
Appearance Black cubic crystals.
CAS number [22398-80-7]
Properties
Density and phase 4.81 g/cm3, solid.
Solubility in water  ? g/100 ml (?°C)
Melting point 1062°C (1335.15 K)
Boiling point No information.
Structure
Molecular shape  ?
Coordination
geometry
 ?
Crystal structure Cubic
Dipole moment  ? D
Electronic Properties
Band gap at 300 K 1.344 eV
Electron effective mass 0.073 me
Hole effective mass 0.64 me
Electron mobility at 300 K 0.46 m²/(V·s)
Hole mobility at 300 K 0.015 m²/(V·s)
Hazards
MSDS External MSDS
Main hazards Carcinogenic.
NFPA 704

2
3
2
 
Flash point Non-flmmable.
R/S statement R: ?
S: ?
RTECS number  ?
Supplementary data page
Structure and
properties
n, εr, etc.
Thermodynamic
data
Phase behaviour
Solid, liquid, gas
Spectral data UV, IR, NMR, MS
Related compounds
Other anions InN, InAs, InSb.
Other cations Gallium phosphide,
Aluminium phosphide
Related compounds Gallium arsenide phosphide
Except where noted otherwise, data are given for
materials in their standard state (at 25°C, 100 kPa)
Infobox disclaimer and references

Indium phosphide (InP) is a binary semiconductor composed of indium and phosphorus. It is used in high-power and high-frequency electronics because of its superior electron velocity with respect to the more common semiconductors silicon and gallium arsenide. It also has a direct bandgap, making it useful for optoelectronics devices like laser diodes.

InP is also used as a substrate for epitaxial indium gallium arsenide based opto-electronic devices.

Indium phosphide also has one of the longest-lived optical phonons of any compound with the zincblende crystal structure.

[edit] Optical properties

The Sellmeier equation that describes how the optical refractive index for indium phosphide depends on wavelength is given by:

n^2(\lambda) = 1  + 7.255 + \frac{2.316 \lambda^2 }{ \lambda^2 - 0.6263^2} + \frac{2.765 \lambda^2 }{ \lambda^2 - 32.935^2}

where λ is the wavelength in micrometres.

This gives refractive index values rising from around 3.21 at 10 µm and 3.32 at 1.5 µm to 3.47 at 1.0 µm.

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