Graft copolymer

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A graft copolymer has polymer chains of one kind growing out of the sides of polymer chains with a different chemical composition.

For example, suppose we perform a free-radical polymerization of styrene in the presence of polybutadiene, a synthetic rubber, which retains one reactive C=C double bond per residue. We get polystyrene chains growing out in either direction from some of the places where there were double bonds, with a one-carbon rearrangement. Or to look at it the other way around, the result is a polystyrene backbone with polybutadiene chains growing out of it in both directions. This is an interesting copolymer variant in that one of the ingredients was a polymer to begin with.

As with block copolymers, the quasi-composite product has properties of both "components". In the example cited, the rubbery chains absorb energy when the substance is hit, so it is much less brittle than ordinary polystyrene. The product is called high-impact polystyrene, or HIPS.