Eriochrome Black T

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Eriochrome Black T

Eriochrome Black T

Systematic (IUPAC) name
sodium (4Z)-4-[(1-hydroxynaphthalen-2-yl)hydrazinylidene]-7-nitro
-3-oxo-naphthalene-1-sulfonate
Identifiers
CAS number 1787-61-7
PubChem         5351620
Chemical data
Formula C20H12N3O7SNa 
Mol. weight 461.381 g/mol
SMILES C1=CC=C2C(=C1)C=CC(=C2O)NN=C3C4=C(C=C
(C=C4)[N+](=O)[O-])C(=CC3=O)S(=O)(=O)[O-].[Na+]
Complete data

Eriochrome Black T is a complexometric indicator that is part of the complexometric titrations, eg. in the water hardness determination process. It is an azo dye.

In its protonated form, Eriochrome Black T is blue and it turns red when it forms complex with calcium, magnesium, or other metal ions. When used as an indicator in an EDTA titration the characteristic blue end-point is reached when sufficient EDTA is added and metal ions form complexes with the EDTA instead of the eriochrome.

Its chemical formula can be written as HOC10H6N=NC10H4(OH)(NO2)SO3Na.

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