Corey-Kim oxidation
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The Corey-Kim oxidation is an oxidation reaction used to synthesise aldehydes and ketones from primary and secondary alcohols.[1][2][3][4][5] The process can be written as follows:
This reaction is a variation of the Swern oxidation.
[edit] See also
[edit] Resources
- ^ E. J. Corey, C. U. Kim (1972). "New and highly effective method for the oxidation of primary and secondary alcohols to carbonyl compounds". Journal of the American Chemical Society 94 (21): 7586 - 7587. DOI:10.1021/ja00776a056.
- ^ E. J. Corey, C. U. Kim (1974). "A method for the oxidation of sec,tert -1,2-diols to α-hydroxy ketones without carbon-carbon cleavage". Tetrahedron Letters 15 (3): 287-290. DOI:10.1016/S0040-4039(01)82195-X.
- ^ S. Katayama, K. Fukuda, T. Watanabe, M. Yamauchi (1988). "Synthesis of 1,3-Dicarbonyl Compounds by the Oxidation of 3-Hydroxycarbonyl Compounds with Corey-Kim Reagent". Synthesis: 178-183. DOI:10.1055/s-1988-27506.
- ^ T. T. Tidwell (1990). "Oxidation of Alcohols by Activated Dimethyl Sulfoxide and Related Reactions: An Update". Synthesis: 857-870. DOI:10.1055/s-1990-27036.
- ^ J. T. Pulkkinen, J. J. Vepsäläinen (1996). "3-Unsubstituted 1,5-Diaryl-2,4-pentanediones and -4-methoxy-2-pentanones: Synthesis via Corresponding 3-Hydroxy Ketones Generated from 2-Isoxazolines". Journal of Organic Chemistry 61 (24): 8604 - 8609. DOI:10.1021/jo960887a.
[edit] External links
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