Talk:Alkane
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I think there should be a mention to the way the different alkanes are related to common fuels, and their physical properties. Methane is a gas at normal condition, and very difficult to liquify, (methane + ethane = natural gas? not sure), butane and propane are also gases, but they can be liquified rather easily, and so they are sold in cilinders, in liquid form. Those cilinders are easily recharged. pentane and hexane, i'm not sure, but heptane and octane are liquid in normal conditions, are main constituents of gasoline. Somewhere in the tens of carbons, the alkanes are solid in normal conditions (paraffine)....etc..
Alkanes differ only slightly from fats and oils. Some discussion of this, would be useful.
Does methylpropane count as propane? The way the article's worded suggests that it is simply an isomer of propane, which is definitely isn't! -- Steinsky
[edit] standardization of chemical articles
I think there should be a standardized form of all chemical articles. It should include a chart with physical properties somewhere, and the same article sections. It would be a tough job to do, considering the vast number of chemicals in the database.
--Edsanville 20:56, 2 Jun 2004 (UTC)
- There is one, at WikiProject Chemistry, however, a template for organic compounds has yet to be established. Gentgeen 21:04, 2 Jun 2004 (UTC)
[edit] Smallest alkane that does not exist
What is the smallest integer Z where CZH2Z+2 does not exist?? 66.245.80.45 16:48, 18 Sep 2004 (UTC)
- He he this looks like a homework question. Okay, you still need to figure it out yourself, so I'm just helping with the arithmetics:
z CzH2z+2 Structure Does it exist? -------------------------------------------------------------- ... 3 C3H8 H3C-CH2-CH3 2 C2H6 H3C-CH3 1 CH4 CH4 0 H2 H2 -1 C-1 ? ...
- --Unconcerned 04:23, 24 Sep 2004 (UTC)
H2 is not considered an alkane because it has no carbon!
[edit] Suggest 5 possible wiki links and 2 possible backlinks for Alkane.
An automated Wikipedia link suggester has some possible wiki link suggestions for the Alkane article:
- Can link Melting point: ... * The density of an alkane is less than water density. * Melting point and boiling point increase with molecular weight and with l... (link to section)
- Can link boiling point: ...an alkane is less than water density. * Melting point and boiling point increase with molecular weight and with length of the main ... (link to section)
- Can link molecular weight: ... density. * Melting point and boiling point increase with molecular weight and with length of the main carbon chain.... (link to section)
- Can link carbon chain: ... increase with molecular weight and with length of the main carbon chain.... (link to section)
- Can link hydrogen atom: ...lysed with [[UV]]. '''2.''' Initiation step (slow step): a hydrogen atom is pulled off from methane... (link to section)
Additionally, there are some other articles which may be able to linked to this one (also known as "backlinks"):
- In Chloroform, can backlink aliphatic hydrocarbon: ...ause vomiting. [[Trichloroethylene]], a related halogenated aliphatic hydrocarbon, later supplanted chloroform as a safer alternative, though...
- In Water contact, can backlink saturated hydrocarbon: ...he pores, which creates a transition zone between the fully saturated hydrocarbon levels and the fully saturated water levels.
Notes: The article text has not been changed in any way; Some of these suggestions may be wrong, some may be right.
Feedback: I like it, I hate it, Please don't link to — LinkBot 11:29, 1 Dec 2004 (UTC)
[edit] Cracking and Reforming
This section doesn't mention reforming at all, only cracking. --82.43.150.220 19:38, 15 May 2006 (UTC)
[edit] Good article nomination failed
- WP:LEAD too short.
- The names of all alkanes end with -ane. ... why? Talk about the history or where the nomenclature comes from.
- Trivial names ... again why are these name kept or why do these compound have multiple names.
- Images imbedded in text isn't recommended, plus they need to have captions.
- Too many lists, at least in the beginning.
- References missing. Use the Cite.php method if possible because it is recommended.
- The line, Alkanes occur both on Earth and in the solar system, however only the first hundred or so, and even then mostly only in traces., doesn't make any sense ... first hundred of what, alkanes, branched alkanes or unbranched alkanes.
- methane and ethane are every day gases, at least methane is emitted by animals through their feces. That is much more relevant than knowing it is present on such comet that is not known to the general public.
- On Titan, the satellite of Saturn, it is believed that there were once large oceans of these and longer chain alkanes: smaller seas of liquid ethane are thought still to exist there. - This is trivia or it pertains tu such articles as Titan or ethane.
- ... produced primarily by forms of Archaea. - maybe should say ... produced primarily by organisms such as Archaea.
- Although they cannot be commercially exploited at the present time, the calorific value of the known methane hydrate fields exceeds the energy content of all the natural gas and oil deposits put together — methane extracted from methane hydrate is considered therefore a candidate for future fuels. - This should not be in the occurence section but in the Properties section.
- Occurence section and Alkanes in nature should be merged or be one under the other as they go toward a same goal, which is showing where these alkanes are present.
- In the Occurence section, the Today, the most important commercial sources ... text and what comes after should go into a section that explains why do we have the alkanes on the earth like Earth's alkane and its sources or so.
- ... within the individual fractions the boiling points lie closely together. - Some explanation on this point .would be greatly appreciated
- ... although the following demarcation is idealized and not perfect. - This statement is pov unless it is referenced or the word idealized is changed.
- The Preparation section is a bit short, needs images of the reactions or needs to be merged with the Purification section.
- The reactions should be labeled with names or be traced back to the publications where they were taken from.
Lincher 21:31, 4 June 2006 (UTC)
- trim down on conformation as it is already covered in Alkane stereochemistry, same goes for reactions of alkanes. Also too many subheaders V8rik 21:57, 4 June 2006 (UTC)
[edit] Nomenclature
It's already mentioned in the article that the first four members of the series don't follow the numerical prefix pattern. Would it be worth mentioning what the prefixes mean?
Briefly: Meth- comes from Greek methu, meaning wine; eth- is linked to ether; prop- comes from pro and pion, Greek words meaning "forward" and "fat", respectively (propane is related to fatty acids); and but- comes from Latin butyrum, meaning butter.
Found this information on the Online Etymology Dictionary.
Maerk 03:12, 21 January 2007 (UTC)
[edit] Basis for a new intro?
Alkanes are chemical compounds that consists only of the elements carbon (C) and hydrogen (H) (i.e. hydrocarbons), wherein each of these atoms are linked together exclusively by single bonds (i.e. saturated compounds).
Since these chemical compounds are saturated, each carbon atom must have 4 bonds (either C-H or C-C bonds), and each hydrogen atom must be joined to a carbon atom (H-C bonds). A series of linked carbon atoms is known as the carbon skeleton or carbon backbone. Typically the number of carbon atoms is often used to define the size of the alkane (e.g. C2-alkane).
Alkanes can be linear (general formula CnH2n+2, where n>0) where the carbon atoms are joined in a snake like structure, cyclic (general formula CnH2n where n>2) where the carbon backbone is linked so as to form a loop, or branched (general formula CnH2n, where n>3) where the carbon backbone splits off in one ore more directions.
The simplest possible alkane (the parent molecule) is methane, CH4. There is no limit to the number of carbon atoms that can be linked together, the only limitation being that the molecule is saturated and is a hydrocarbon. Saturated oils and waxes are example of larger alkanes where the number of carbons in the carbon backbone tend to be great than 10.
The trivial name (non-systematic) for alkanes is paraffins, or collectively as the paraffin series. Trivial names for compounds usually are a historical artefact, often steming from industrial practices. The term paraffins almost certainly stems from the petrochemical industry. Branched-chain alkanes are called isoparaffins. Cycloalkanes (also called naphthenes) are alkanes that containing one or more rings. The use of the term "paraffin" is a general term and often does not distinguish between a pure compounds and mixtures of isomers with the same chemical formula (i.e. like a chemical anagram) e.g. pentane and isopentane. --Quantockgoblin 22:55, 5 February 2007 (UTC)
- Sound's good. I've added it in. --Rifleman 82 23:37, 5 February 2007 (UTC)
[edit] Nomenclature of alkanes
The Geneva system is based on identifying hydrocarbon chains, most of which are named systematically with a Greek numerical prefix denoting the number of carbons and the suffix "-ane".[citation needed]
Wilhelm Hofmann suggested systematizing nomenclature by using the whole sequence of vowels a, e, i, o and u to create suffixes -ane, -ene, -ine (or -yne), -one, -une, for the hydrocarbons. Only the first three caught on for naming hydrocarbons with single, double and triple bonds.
[edit] Linear Alkanes
Straight-chain alkanes are sometimes indicated by the prefix n- (for normal) where a non-linear isomer exists. Although this is not strictly necessary, the usage is still common in cases where there is an important difference in properties between the straight-chain and branched-chain isomers: e.g. n-hexane or cyclohexane 2- or 3-methylpentane.
The first four members of the series (in terms of number of carbon atoms) are named as follows:
Alkanes with five or more carbon atoms are named by adding the suffix -ane to the appropriate numerical multiplier with elision of a terminal -a- from the basic numerical term. Hence, pentane, C5H12; hexane, C6H14; heptane, C7H16; octane, C8H18; etc. For a more complete list, see List of alkanes.
[edit] Branched alkanes
Simple branched alkanes often have a prefix "iso-" to distinguish them from linear alkanes.
The key steps in the naming of more complicate branched alkanes are as follows:
- Identify the longest linear chain of carbon atoms.
- This portion is named as if it where a liner alkane (i.e. 3 linear carbon atoms would be a propane).
- One of the terminal ends of this chain is numbered 1. The terminus which has the fewest carbon atoms from the branch is numbered 1.
- the nomenclature is determined for the branching group in a similar fashion as above.
- the compound is then named (branching number e.g. 2)-(name of branching group, e.g. methyl)-(name of longest linear chain, e.g. propane) so as to give you the alkane's name, e.g. 2-methyl-propane which is shown right.
[edit] Cyclic alkanes
Simple cyclic alkanes often have a prefix "cyclo-" to distinguish them from linear or branched alkanes. Cycloalkanes are named as per linear alkanes with respect to the number of carbon atoms e.g. cyclopentane is a alkane with 5 carbon atoms joined up in a five membered ring.
[edit] Trivial names
The trivial (non-systematic) name for alkanes is "paraffins". Collectively, alkanes are known as the paraffin series. Trivial names for compounds are usually historical artefacts. They were coined before the development of systematic names, and have been retained due to familiar usage in industry.
The term paraffins almost certainly stems from the petrochemical industry. Branched-chain alkanes are called isoparaffins. Cycloalkanes (also called naphthenes) are alkanes that containing one or more rings. The use of the term "paraffin" is a general term and often does not distinguish between a pure compounds and mixtures of isomers with the same chemical formula (i.e. like a chemical anagram) e.g. pentane and isopentane.
- Examples
The following trivial names are retained in the IUPAC system:
- isobutane for 2-methylpropane
- isopentane for 2-methylbutane
- neopentane for 2,2-dimethylpropane
- Will wait for at least one postive review before replacing text -- Quantockgoblin 00:15, 6 February 2007 (UTC)
[edit] alkane redirects
I noticed that the following alkanes mention in this article:
Just have a rediredt back to alkane, which is not very helpful - delete redirect pages? — The preceding unsigned comment was added by Quantockgoblin (talk • contribs) 15:00, 6 February 2007 (UTC).
[edit] Isomers list
In the "Isomerism" section, the text says "for alkanes with 1 to 12 carbon atoms, the number of isomers equals" but the subsequent list only contains C1-C4 and C12. Should we include C5-C11 as the intro says the list will contain? Or should we add a C15ish entry and adjust the text to indicate simply "as the number of carbons increases, the number of possible isomers increases rapidly" (or something...not sure two "increases" is good there)? I sorta like the latter, as it illustrates the point about structural possibilities and an exhaustive list doesn't really serve a purpose. DMacks 03:08, 6 April 2007 (UTC)
Mathematicians have this vertical ...
it looks like this . .
. .
. .
when denoting series, while leaving out some entries. How about that? --Rifleman 82 07:13, 6 April 2007 (UTC)
