Triiodide

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Space-filling model of the triiodide anion
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Space-filling model of the triiodide anion

Triiodide is an anion composed of three iodine atoms.

The following equilibrium :

I2 + I → I3

gives rise to the triiodide ion in solution. The Lewis base is the iodide ion and the Lewis acid is iodine. The reaction is endothermic. The central atom of I3 is sp3d hybridised, and the ion thus has linear shape according to VSEPR theory. Triiodide appears yellow in low concentration, and brown at higher concentration.


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