Schiemann reaction

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The Schiemann reaction (also called the Balz-Schiemann reaction) is a chemical reaction in which anilines (1) are transformed to aryl fluorides (3) via diazonium fluoroborates (2).[1][2]

The Schiemann reaction

Swain and Rogers have studied the mechanism of the diazonium fluoroborate decomposition to aryl fluorides.[3]

[edit] References

  1. ↑  Balz, G.; Schiemann, G. Ber. 1927, 60, 1186.
  2. ↑  Roe, A. Org. React. 1949, 5, 193. (Review)
  3. ↑  Swain, C. G.; Rogers, R. J. J. Am. Chem. Soc. 1975, 97, 799-800. (DOI:10.1021/ja00837a019)


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