Potassium ferrocyanide

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Small yellow crystals
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Small yellow crystals

Potassium ferrocyanide (K4Fe(CN)6·3H2O), also known as yellow prussiate of potash or potassium hexacyanoferrate(II), is a coordination compound forming lemon-yellow monoclinic crystals at room temperature and decomposing at its boiling point. It is insoluble in alcohol but a litre of water can dissolve just under three hundred grams of the crystals, and the solution can react with acid to release hydrogen cyanide gas. The resulting hydrogen cyanide (HCN) boils at 26 °C and, being slightly lighter than air, quickly evaporates clear of the release point.

On February 20, 2002 four Moroccans were arrested while in possession of detailed maps of the United States embassy in Rome, the Rome water supply network, and four kilograms of potassium ferrocyanide. This chemical is almost non-toxic itself and when combined with ferric salts it forms the Prussian blue, which is sometimes used as an antidote, but it will release the extremely toxic Hydrogen cyanide when combined with stronger acids.

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