Lemon battery

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The lemon battery is an experiment proposed as a project in many science textbooks around the world. [1]. It consists of inserting two different metallic objects, for example a galvanized nail and a copper coin, into a lemon. These two objects work as electrodes, causing an electrochemical reaction which generates a small amount of electricity.

A lemon cell battery is made with a lemon and two metallic electrodes of different metals. In practice, a single lemon cell is incapable of lighting a light bulb.
A lemon cell battery is made with a lemon and two metallic electrodes of different metals. In practice, a single lemon cell is incapable of lighting a light bulb.

The aim of this experiment is to show students how batteries work. After the battery is assembled, a multimeter can be used to check the generated voltage. In order for a more visible effect to be produced, the battery can be used to power a LED. Since the produced voltage is typically insufficient to power a standard LED, two or more batteries are connected in series.

In a lemon battery, both oxidation and reduction occur. At the anode, zinc is oxidised:

Zn → Zn2+ + 2 e-

At the cathode, hydrogen is reduced:

2H++ 2e- → H2

Potatoes [2], apples, or any other fruit or vegetable containing acid or other electrolyte can be used, but lemons are preferred because of their higher acidity [3] [4]. Other metal combinations (such as magnesium-copper) are more efficient, but zinc and copper are usually used because they are reasonably safe and easy to obtain.

Using a magnesium strip instead of zinc approximately doubles the current produced by the lemon cell (approx. 240 µA with zinc to about 400 µA with magnesium) and increases the voltage (.97 V with zinc to 1.6 V with magnesium). These numbers, of course, depend upon your lemons.

[edit] Warning

This experiment may leave the lemon's juice poisonous because of dissolved copper salts.


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