User:Karlhahn/oldSand
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Material that has been retired from my main sandbox
Contents |
[edit] Liquid/Vapor Equilibrium Data
Vapor over Anhydrous Ammonia | ||||
---|---|---|---|---|
Temp. | Pressure | ρ of liquid | ρ of vapor | ΔvapH |
–78 °C | 5.90 kPa | |||
–75 °C | 7.93 kPa | 0.73094 g/cm3 | 7.8241×10–5 g/cm3 | |
–70 °C | 10.92 kPa | 0.72527 g/cm3 | 1.1141×10–4 g/cm3 | |
–65 °C | 15.61 kPa | 0.71953 g/cm3 | 1.5552×10–4 g/cm3 | |
–60 °C | 21.90 kPa | 0.71378 g/cm3 | 2.1321×10–4 g/cm3 | |
–55 °C | 30.16 kPa | 0.70791 g/cm3 | 2.8596×10–4 g/cm3 | |
–50 °C | 40.87 kPa | 0.70200 g/cm3 | 3.8158×10–4 g/cm3 | 1417 J/g |
–45 °C | 54.54 kPa | 0.69604 g/cm3 | 4.9940×10–4 g/cm3 | 1404 J/g |
–40 °C | 71.77 kPa | 0.68999 g/cm3 | 6.4508×10–4 g/cm3 | 1390 J/g |
–35 °C | 93.19 kPa | 0.68385 g/cm3 | 8.2318×10–4 g/cm3 | 1375 J/g |
–30 °C | 119.6 kPa | 0.67764 g/cm3 | 1.0386×10–3 g/cm3 | 1361 J/g |
–25 °C | 151.6 kPa | 0.67137 g/cm3 | 1.2969×10–3 g/cm3 | 1345 J/g |
–20 °C | 190.2 kPa | 0.66503 g/cm3 | 1.6039×10–3 g/cm3 | 1330 J/g |
–15 °C | 236.3 kPa | 0.65854 g/cm3 | 1.9659×10–3 g/cm3 | 1314 J/g |
–10 °C | 290.8 kPa | 0.65198 g/cm3 | 2.3874×10–3 g/cm3 | 1297 J/g |
–5 °C | 354.8 kPa | 0.64533 g/cm3 | 2.8827×10–3 g/cm3 | 1280 J/g |
0 °C | 429.4 kPa | 0.63857 g/cm3 | 3.4528×10–3 g/cm3 | 1263 J/g |
5 °C | 515.7 kPa | 0.63167 g/cm3 | 4.1086×10–3 g/cm3 | 1245 J/g |
10 °C | 614.9 kPa | 0.62469 g/cm3 | 4.8593×10–3 g/cm3 | 1226 J/g |
15 °C | 728.3 kPa | 0.61755 g/cm3 | 5.7153×10–3 g/cm3 | 1207 J/g |
20 °C | 857.1 kPa | 0.61028 g/cm3 | 6.6876×10–3 g/cm3 | 1187 J/g |
25 °C | 1003 kPa | 0.60285 g/cm3 | 7.7882×10–3 g/cm3 | 1167 J/g |
30 °C | 1166 kPa | 0.59524 g/cm3 | 9.0310×10–3 g/cm3 | 1146 J/g |
35 °C | 1350 kPa | 0.58816 g/cm3 | 1.0431×10–2 g/cm3 | 1124 J/g |
40 °C | 1554 kPa | 0.57948 g/cm3 | 1.2006×10–2 g/cm3 | 1101 J/g |
45 °C | 1781 kPa | 0.57130 g/cm3 | 1.3775×10–2 g/cm3 | 1083 J/g |
50 °C | 2032 kPa | 0.56287 g/cm3 | 1.5761×10–2 g/cm3 | 1052 J/g |
55 °C | 2310 kPa | 0.55420 g/cm3 | ||
60 °C | 2613 kPa | 0.54523 g/cm3 | 2.05×10–2 g/cm3 | |
65 °C | 2947 kPa | 0.53596 g/cm3 | ||
70 °C | 3312 kPa | 0.52632 g/cm3 | 2.65×10–2 g/cm3 | |
75 °C | 3711 kPa | 0.51626 g/cm3 | ||
80 °C | 4144 kPa | 0.50571 g/cm3 | 3.41×10–2 g/cm3 | |
85 °C | 4614 kPa | 0.49463 g/cm3 | ||
90 °C | 5123 kPa | 0.48290 g/cm3 | 4.39×10–2 g/cm3 | |
95 °C | 5672 kPa | 0.47041 g/cm3 | ||
100 °C | 6264 kPa | 0.45693 g/cm3 | 5.68×10–2 g/cm3 |
The table above gives properties of the vapor/liquid equilibrium of anhydrous ammonia at various temperatures. The second column is vapor pressure in kPa. The third column is the density of the liquid phase. The fourth column is the density of the vapor. The fifth column is the heat of vaporization needed to convert one gram of liquid to vapor.
[edit] Equilibrium of vapor over aqueous solution
Vapor over Aqueous Ammonia Solution[1] | |||
---|---|---|---|
Temp. | %wt NH3 | Partial Pressure NH3 |
Partial Pressure H2O |
0 °C | 4.72 | 1.52 kPa | 0.68 kPa |
9.15 | 3.31 kPa | 0.71 kPa | |
14.73 | 6.84 kPa | 0.55 kPa | |
19.62 | 11.0 kPa | 0.40 kPa | |
22.90 | 14.9 kPa | 0.37 kPa | |
10 °C | 4.16 | 2.20 kPa | 1.21 kPa |
8.26 | 4.96 kPa | 1.17 kPa | |
12.32 | 8.56 kPa | 1.01 kPa | |
15.88 | 12.68 kPa | 0.93 kPa | |
20.54 | 19.89 kPa | 0.83 kPa | |
21.83 | 22.64 kPa | 0.73 kPa | |
19.9 °C | 4.18 | 3.65 kPa | 2.19 kPa |
6.50 | 6.11 kPa | 2.15 kPa | |
6.55 | 6.13 kPa | 2.13 kPa | |
7.72 | 7.49 kPa | 2.08 kPa | |
10.15 | 10.75 kPa | 2.01 kPa | |
10.75 | 11.51 kPa | 1.96 kPa | |
16.64 | 22.14 kPa | 1.72 kPa | |
19.40 | 28.74 kPa | 1.64 kPa | |
23.37 | 40.32 kPa | 1.37 kPa | |
30.09 °C | 3.93 | 5.49 kPa | 4.15 kPa |
7.43 | 11.51 kPa | 3.89 kPa | |
9.75 | 16.00 kPa | 3.80 kPa | |
12.77 | 23.33 kPa | 3.55 kPa | |
17.76 | 38.69 kPa | 3.31 kPa | |
17.84 | 38.81 kPa | 3.24 kPa | |
21.47 | 53.94 kPa | 2.95 kPa | |
40 °C | 3.79 | 8.15 kPa | 7.13 kPa |
7.36 | 17.73 kPa | 6.76 kPa | |
11.06 | 29.13 kPa | 6.55 kPa | |
15.55 | 47.14 kPa | 5.52 kPa | |
17.33 | 57.02 kPa | ||
20.85 | 76.81 kPa | 5.04 kPa | |
50 °C | 3.29 | 10.54 kPa | 11.95 kPa |
5.90 | 20.17 kPa | 11.61 kPa | |
8.91 | 32.88 kPa | 11.07 kPa | |
11.57 | 45.56 kPa | 10.75 kPa | |
14.15 | 60.18 kPa | 10.27 kPa | |
14.94 | 64.94 kPa | 10.03 kPa | |
60 °C | 3.86 | 18.25 kPa | 19.21 kPa |
5.77 | 28.78 kPa | ||
7.78 | 40.05 kPa | 18.47 kPa | |
9.37 | 50.09 kPa | 18.07 kPa | |
9.37 | 63.43 kPa | 17.39 kPa |
[edit] Hebrew Calendar
[edit] Summary of Calendar Calculations
The audience for this section is computer programmers who wish to write software that accurately computes dates in the Hebrew calendar. The following details are sufficient to generate such software.
- 1) The Hebrew calendar is computed by lunations. One lunation is reckoned at 29 days, 12 hours, 44 minutes, 3⅓ seconds, or equivalently 765433 halakim = 29 days, 13753 halakim.
- 2) A common year must be either 353, 354, or 355 days; a leap year must be 383, 384, or 385 days. A 353 or 383 day year is called kesidrah. A 354 or 384 day year is shelemah. A 355 or 385 day year is haserah.
- 3) Leap years follow a 19 year schedule in which years 3, 6, 8, 11, 14, 17, and 19 are leap years. The Jewish year 5752 (which starts in Gregorian year 1991) is the first year of a cycle.
- 4) 19 years is the same as 235 lunations.
- 5) The months are Tishri, Heshvan, Kislev, Tebeth, Shebhat, Adar, Nisan, Iyyar, Sivan, Tammuz, Av, and Elul. In addition, a second Adar (also called Veadar, Adar II, or Adar Sheni) is added in leap years. When added, it follows Adar.
- 6) Each month has either 29 or 30 days. A 30 day month is male, a 29 day month is haser.
-
- Nisan, Sivan, Av, Tishri, and Shebhat are always male.
-
- Iyyar, Tammuz, Elul, Tebeth, and Adar II are always haser.
-
- Adar is male in leap years, haser in common years.
-
- Heshvan and Kislev vary, but when they differ, Heshvan is haser and Kislev is male.
- 7) Tishri 1st (Rosh Hashana) is the day of a molad (new moon) unless certain conditions (dahiyyah sing; dahiyyot pl) exist.
-
- a) This dahiyyah exists whenever Tishri 10 (Yom Kippur) would fall on a Friday or a Sunday, or if Tishri 21 (7th day of Sukkot) would fall on a Saturday. This is equivalent to the molad being on Sunday, Wednesday, or Friday. Whenever this happens, Tishri 1 is delayed by 1 day.
-
- b) This dahiyyah exists whenever the molad occurs on or after noon. When this dahiyyah exists, Tishri 1 is delayed by 1 day. If this causes dahiyyah A to exist, Tishri 1 is delayed an additional day.
-
- c) If the year is to be a common year and the molad falls on a Tuesday on or after 3:11:20 am (3 hours 204 halakim) Jerusalem time, Tishri 1 is delayed by 2 days. This is because if it weren't delayed, the resulting year would be 356 days long.
-
- d) If the new year follows a leap year and the molad is on a Monday on or after 9:32:43 and one third seconds (9 hours 589 halakim), Tishri 1 is delayed 1 day. This is because if it weren't, the preceding year would have only 382 days.
- 8) Delays are implemented by adding a day to Kislev of the preceding year, making it male. If Kislev is already male, the day is added to Heshvan of the preceding year, making it male also. If a delay of 2 days is called for, both Heshvan and Kislev of the preceding year become male.
- 9) The molad of 08-Sep-1991, which is Rosh Hashana of Hebrew yer, 5752, is Julian day, 2448509 plus 3294 halakim.
[edit] Future Project: Tide Prediction
Plan to explain the method of harmonic constituents as detailed in U.S. Govt. Special Publication 92.
[edit] Reorganize Heat Capacity Ratio Table
Heat Capacity Ratio for various gases[2][3] | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|
Temp. | Gas | γ | Temp. | Gas | γ | Temp. | Gas | γ | ||
–181°C | H2 | 1.597 | –76°C | H2 | 1.453 | 20°C | H2 | 1.41 | ||
100°C | H2 | 1.404 | 400°C | H2 | 1.387 | 1000°C | H2 | 1.358 | ||
2000°C | H2 | 1.318 | 20°C | He | 1.66 | 20°C | H2O | 1.33 | ||
100°C | H2O | 1.324 | 200°C | H2O | 1.310 | –180°C | Ar | 1.76 | ||
20°C | Ar | 1.67 | 0°C | Dry Air | 1.403 | 20°C | Dry Air | 1.40 | ||
100°C | Dry Air | 1.401 | 200°C | Dry Air | 1.398 | 400°C | Dry Air | 1.393 | ||
1000°C | Dry Air | 1.365 | 1400°C | Dry Air | 1.341 | 2000°C | Dry Air | 1.088 | ||
0°C | CO2 | 1.310 | 20°C | CO2 | 1.30 | 100°C | CO2 | 1.281 | ||
400°C | CO2 | 1.235 | 1000°C | CO2 | 1.195 | 20°C | CO | 1.40 | ||
–181°C | O2 | 1.45 | –76°C | O2 | 1.415 | 20°C | O2 | 1.40 | ||
100°C | O2 | 1.399 | 200°C | O2 | 1.397 | 400°C | O2 | 1.394 | ||
20°C | NO | 1.40 | 20°C | N2O | 1.31 | –181°C | N2 | 1.47 | ||
15°C | N2 | 1.404 | 20°C | Cl2 | 1.34 | –115°C | CH4 | 1.41 | ||
–74°C | CH4 | 1.35 | 20°C | CH4 | 1.32 | 19°C | Ne | 1.64 | ||
19°C | Kr | 1.68 | 19°C | Xe | 1.66 | 15°C | SO2 | 1.29 | ||
360°C | Hg | 1.67 |
Heat Capacity Ratio for various gases[4][5] | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|
Temp. | Gas | γ | Temp. | Gas | γ | Temp. | Gas | γ | ||
–181°C | H2 | 1.597 | 200°C | Dry Air | 1.398 | 20°C | NO | 1.40 | ||
–76°C | 1.453 | 400°C | 1.393 | 20°C | N2O | 1.31 | ||||
20°C | 1.41 | 1000°C | 1.365 | –181°C | N2 | 1.47 | ||||
100°C | 1.404 | 2000°C | 1.088 | 15°C | 1.404 | |||||
400°C | 1.387 | 0°C | CO2 | 1.310 | 20°C | Cl2 | 1.34 | |||
1000°C | 1.358 | 20°C | 1.30 | –115°C | CH4 | 1.41 | ||||
2000°C | 1.318 | 100°C | 1.281 | –74°C | 1.35 | |||||
20°C | He | 1.66 | 400°C | 1.235 | 20°C | 1.32 | ||||
20°C | H2O | 1.33 | 1000°C | 1.195 | 15°C | NH3 | 1.310 | |||
100°C | 1.324 | 20°C | CO | 1.40 | 19°C | Ne | 1.64 | |||
200°C | 1.310 | –181°C | O2 | 1.45 | 19°C | Xe | 1.66 | |||
–180°C | Ar | 1.76 | –76°C | 1.415 | 19°C | Kr | 1.68 | |||
20°C | 1.67 | 20°C | 1.40 | 15°C | SO2 | 1.29 | ||||
0°C | Dry Air | 1.403 | 100°C | 1.399 | 360°C | Hg | 1.67 | |||
20°C | 1.40 | 200°C | 1.397 | 15°C | C2H6 | 1.22 | ||||
100°C | 1.401 | 400°C | 1.394 | 16°C | C3H8 | 1.13 |
[edit] Translating Water (data page) equivalent from German
[edit] Current version of translation
[edit] Physical and Thermodynamic Tables
In the following tables, values are temperature dependent and to a lesser degree pressure dependent, and are arranged by state of aggregation (s=solid, lq=liquid, g=gas), which are clearly a function of temperature and pressure. All of the data were computed from data given in "Formulation of the Thermodynamic Properties of Ordinary Water Substance for Scientific and General Use" (1984). This applies to:
- T - temperature in degrees celsius
- V - specific volume in decimeter3 per kilogram
- H - specific enthalpy in kJ per kilogram
- U - internal energy in kJ per kilogram
- S - specific entropy in kJ per kilogram-Kelvin
- cp - specific (constant pressure) heat capacity in kJ per kilogram-Kelvin
- γ - Thermal expansion coefficient as 10–3 per Kelvin
- λ - Heat conductivity in milliwatt per meter-Kelvin
- η - Viscosity in μPa-seconds
- σ - Surface Tension millinewtons per meter
[edit] Standard conditions
In the following table, material data is given for standard pressure of 0.1 MPa (equivalent to 1 bar). Up to 99.63 °C (the boiling point of water), at this pressure water exists as a liquid. Above that, it exists as water vapor.
Water/Steam Data Table at Standard Pressure (0.1 MPa) | ||||||||||
T °C | V dm³/kg |
H kJ/kg |
U kJ/kg |
S kJ/(kg·K) |
cp kJ/(kg·K) |
γ 10–3/K |
λ mW / (m·K) |
η μPa·s |
σ1 mN/m |
|
0 | lq | 1.0002 | 0.06 | -0.04 | -0.0001 | 4.228 | -0.080 | 561.0 | 1792 | 75.65 |
5 | 1.0000 | 21.1 | 21.0 | 0.076 | 4.200 | 0.011 | 570.6 | 1518 | 74.95 | |
10 | 1.0003 | 42.1 | 42.0 | 0.151 | 4.188 | 0.087 | 580.0 | 1306 | 74.22 | |
15 | 1.0009 | 63.0 | 62.9 | 0.224 | 4.184 | 0.152 | 589.4 | 1137 | 73.49 | |
20 | 1.0018 | 83.9 | 83.8 | 0.296 | 4.183 | 0.209 | 598.4 | 1001 | 72.74 | |
25 | 1.0029 | 104.8 | 104.7 | 0.367 | 4.183 | 0.259 | 607.2 | 890.4 | 71.98 | |
30 | 1.0044 | 125.8 | 125.7 | 0.437 | 4.183 | 0.305 | 615.5 | 797.7 | 71.20 | |
35 | 1.0060 | 146.7 | 146.6 | 0.505 | 4.183 | 0.347 | 623.3 | 719.6 | 70.41 | |
40 | 1.0079 | 167.6 | 167.5 | 0.572 | 4.182 | 0.386 | 630.6 | 653.3 | 69.60 | |
45 | 1.0099 | 188.5 | 188.4 | 0.638 | 4.182 | 0.423 | 637.3 | 596.3 | 68.78 | |
50 | 1.0121 | 209.4 | 209.3 | 0.704 | 4.181 | 0.457 | 643.6 | 547.1 | 67.95 | |
60 | 1.0171 | 251.2 | 251.1 | 0.831 | 4.183 | 0.522 | 654.4 | 466.6 | 66.24 | |
70 | 1.0227 | 293.1 | 293.0 | 0.955 | 4.187 | 0.583 | 663.1 | 404.1 | 64.49 | |
80 | 1.0290 | 335.0 | 334.9 | 1.075 | 4.194 | 0.640 | 670.0 | 354.5 | 62.68 | |
90 | 1.0359 | 377.0 | 376.9 | 1.193 | 4.204 | 0.696 | 675.3 | 314.6 | 60.82 | |
99.63 | lq | 1.0431 | 417.5 | 417.4 | 1.303 | 4.217 | 0.748 | 679.0 | 283.0 | 58.99 |
g | 1694.3 | 2675 | 2505 | 7.359 | 2.043 | 2.885 | 25.05 | 12.26 | – | |
100 | g | 1696.1 | 2675 | 2506 | 7.361 | 2.042 | 2.881 | 25.08 | 12.27 | 58.92 |
200 | 2172.3 | 2874 | 2657 | 7.833 | 1.975 | 2.100 | 33.28 | 16.18 | 37.68 | |
300 | 2638.8 | 3073 | 2810 | 8.215 | 2.013 | 1.761 | 43.42 | 20.29 | 14.37 | |
500 | 3565.5 | 3488 | 3131 | 8.834 | 2.135 | 1.297 | 66.970 | 28.57 | – | |
750 | 4721.0 | 4043 | 3571 | 9.455 | 2.308 | 0.978 | 100.30 | 38.48 | – | |
1000 | 5875.5 | 4642 | 4054 | 9.978 | 2.478 | 0.786 | 136.3 | 47.66 | – | |
1 The values for surface tension for the liquid section of the table are for a liquid/air interface. Values for the gas section of the table are for a liquid/saturated steam interface. |
[edit] Triple Point
In the following table, material data is given with a pressure of 0.0006117 MPa (equivalent to 0.006117 bar). Up to a temperature of 0.01 °C, the triple point of water, water normally exists as ice, except for supercooled water, for which one data point is tabulated here. At the triple point ice can exist together with both liquid water and vapor. At higher temperatures the data is for water vapor only.
Water/Steam Data Table at Triple Point Pressure (0.0006117 MPa) | |||||||||
T °C | V dm³/kg |
H kJ/kg |
U kJ/kg |
S kJ/(kg·K) |
cp kJ/(kg·K) |
γ 10–3/K |
λ mW / (m·K) |
η μPa·s |
|
0 | lq | 1.0002 | –0.04 | –0.04 | –0.0002 | 4.339 | –0.081 | 561.0 | 1792 |
0.1 | s | 1.0908 | –333.4 | –333.4 | –1.221 | 1.93 | 0.1 | 2.2 | – |
lq | 1.0002 | 0.0 | 0 | 0 | 4.229 | –0.080 | 561.0 | 1791 | |
g | 205986 | 2500 | 2374 | 9.154 | 1.868 | 3.672 | 17.07 | 9.22 | |
5 | g | 209913 | 2509 | 2381 | 9.188 | 1.867 | 3.605 | 17.33 | 9.34 |
10 | 213695 | 2519 | 2388 | 9.222 | 1.867 | 3.540 | 17.60 | 9.46 | |
15 | 217477 | 2528 | 2395 | 9.254 | 1.868 | 3.478 | 17.88 | 9.59 | |
20 | 221258 | 2537 | 2402 | 9.286 | 1.868 | 3.417 | 18.17 | 9.73 | |
25 | 225039 | 2547 | 2409 | 9.318 | 1.869 | 3.359 | 18.47 | 9.87 | |
30 | 228819 | 2556 | 2416 | 9.349 | 1.869 | 3.304 | 18.78 | 10.02 | |
35 | 232598 | 2565 | 2423 | 9.380 | 1.870 | 3.249 | 19.10 | 10.17 | |
40 | 236377 | 2575 | 2430 | 9.410 | 1.871 | 3.197 | 19.43 | 10.32 | |
45 | 240155 | 2584 | 2437 | 9.439 | 1.872 | 3.147 | 19.77 | 10.47 | |
50 | 243933 | 2593 | 2444 | 9.469 | 1.874 | 3.098 | 20.11 | 10.63 | |
60 | 251489 | 2612 | 2459 | 9.526 | 1.876 | 3.004 | 20.82 | 10.96 | |
70 | 259043 | 2631 | 2473 | 9.581 | 1.880 | 2.916 | 21.56 | 11.29 | |
80 | 266597 | 2650 | 2487 | 9.635 | 1.883 | 2.833 | 22.31 | 11.64 | |
90 | 274150 | 2669 | 2501 | 9.688 | 1.887 | 2.755 | 23.10 | 11.99 | |
100 | 281703 | 2688 | 2515 | 9.739 | 1.891 | 2.681 | 23.90 | 12.53 | |
200 | 357216 | 2879 | 2661 | 10.194 | 1.940 | 2.114 | 32.89 | 16.21 | |
300 | 432721 | 3076 | 2811 | 10.571 | 2.000 | 1.745 | 43.26 | 20.30 | |
500 | 583725 | 3489 | 3132 | 11.188 | 2.131 | 1.293 | 66.90 | 28.57 | |
750 | 772477 | 4043 | 3571 | 11.808 | 2.307 | 0.977 | 100.20 | 38.47 | |
1000 | 961227 | 4642 | 4054 | 12.331 | 2.478 | 0.785 | 136.30 | 47.66 |
[edit] Saturated Vapor Pressure
The following table is based on different, complementary sources and approximation formulas, whose values are of various quality and accuracy. The values in the temperature range of –100 °C to 100 °C were inferred from D. Sunday (1982) and are quite uniform and exact. The values in the temperature range of the boiling point of the water up to the critical point (100 °C to 374 °C), are drawn from different sources and are substantially less accurate, hence they should be understood and used also only as approximate values.[6][7][8][9]
To use the values corrctly, consider the following points:
- The values apply only to smooth interfaces and in the absence other gases or gas mixtures such as air. Hence they apply only to pure phases and need a correction factor for systems in which air is present.
- The values were not computed according formulas widely used in the US, but using somewhat more exact formulas (see below), which can also also be used to compute further values in the appropriate temperature ranges.
- The saturated steam pressure over water in the temperature range of –100 °C to –50 °C is only extrapolated.
- The values have various units (Pa, hPa or bar), which must be considered when reading them.
[edit] Formulas
The table values for –100 °C to 100 °C were computed by the following formulas, where T is in Kelvins and vapor pressures, Pw and Pi are in Pa.
Over Liquid Water
- loge(Pw) = –6094.4642 T–1 + 21.1249952 – 2.724552×10–2 T + 1.6853396×10–5 T2 + 2.4575506 loge(T)
For Temperature Range: 173.15 K to 373.15 K or equivalently –100 °C to 100 °C
Over Ice
- loge(Pi) = –5504.4088 T–1 – 3.5704628 – 1.7337458×10–2 T + 6.5204209×10–6 T2 + 6.1295027 loge(T)
For temperature range: 173.15 K to 273.15 K or equivalently –100 °C to 0 °C
[edit] Triple point
An important basic value, which is not registered in the table, is the saturated vapor pressure at the triple point of water. The internationally accepted value according to measurements of Guildner, Johnson and Jones (1976) amounts to:
Values of Saturated Vapor Pressure of Water | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|
Temp. t in °C |
Pi(t) over ice in Pa |
Pw(t) over water in Pa |
Temp. t in °C |
Pw(t) over water in hPa |
Temp. t in °C |
P(t) in bar |
Temp. t in °C |
P(t) in bar |
Temp. t in °C |
P(t) in bar |
-100 | 0.0013957 | 0.0036309 | 0 | 6.11213 | 100 | 1.01 | 200 | 15.55 | 300 | 85.88 |
-99 | 0.0017094 | 0.0044121 | 1 | 6.57069 | 101 | 1.05 | 201 | 15.88 | 301 | 87.09 |
-98 | 0.0020889 | 0.0053487 | 2 | 7.05949 | 102 | 1.09 | 202 | 16.21 | 302 | 88.32 |
-97 | 0.002547 | 0.0064692 | 3 | 7.58023 | 103 | 1.13 | 203 | 16.55 | 303 | 89.57 |
-96 | 0.0030987 | 0.0078067 | 4 | 8.13467 | 104 | 1.17 | 204 | 16.89 | 304 | 90.82 |
-95 | 0.0037617 | 0.0093996 | 5 | 8.72469 | 105 | 1.21 | 205 | 17.24 | 305 | 92.09 |
-94 | 0.0045569 | 0.011293 | 6 | 9.35222 | 106 | 1.25 | 206 | 17.60 | 306 | 93.38 |
-93 | 0.0055087 | 0.013538 | 7 | 10.0193 | 107 | 1.30 | 207 | 17.96 | 307 | 94.67 |
-92 | 0.0066455 | 0.016195 | 8 | 10.728 | 108 | 1.34 | 208 | 18.32 | 308 | 95.98 |
-91 | 0.0080008 | 0.019333 | 9 | 11.4806 | 109 | 1.39 | 209 | 18.70 | 309 | 97.31 |
-90 | 0.0096132 | 0.023031 | 10 | 12.2794 | 110 | 1.43 | 210 | 19.07 | 310 | 98.65 |
-89 | 0.011528 | 0.027381 | 11 | 13.1267 | 111 | 1.48 | 211 | 19.46 | 311 | 100 |
-88 | 0.013797 | 0.032489 | 12 | 14.0251 | 112 | 1.53 | 212 | 19.85 | 312 | 101.37 |
-87 | 0.016482 | 0.038474 | 13 | 14.9772 | 113 | 1.58 | 213 | 20.25 | 313 | 102.75 |
-86 | 0.019653 | 0.045473 | 14 | 15.9856 | 114 | 1.64 | 214 | 20.65 | 314 | 104.15 |
-85 | 0.02339 | 0.053645 | 15 | 17.0532 | 115 | 1.69 | 215 | 21.06 | 315 | 105.56 |
-84 | 0.027788 | 0.063166 | 16 | 18.1829 | 116 | 1.75 | 216 | 21.47 | 316 | 106.98 |
-83 | 0.032954 | 0.074241 | 17 | 19.3778 | 117 | 1.81 | 217 | 21.89 | 317 | 108.43 |
-82 | 0.039011 | 0.087101 | 18 | 20.6409 | 118 | 1.86 | 218 | 22.32 | 318 | 109.88 |
-81 | 0.046102 | 0.10201 | 19 | 21.9757 | 119 | 1.93 | 219 | 22.75 | 319 | 111.35 |
-80 | 0.054388 | 0.11925 | 20 | 23.3854 | 120 | 1.99 | 220 | 23.19 | 320 | 112.84 |
-79 | 0.064057 | 0.13918 | 21 | 24.8737 | 121 | 2.05 | 221 | 23.64 | 321 | 114.34 |
-78 | 0.07532 | 0.16215 | 22 | 26.4442 | 122 | 2.12 | 222 | 24.09 | 322 | 115.86 |
-77 | 0.088419 | 0.1886 | 23 | 28.1006 | 123 | 2.18 | 223 | 24.55 | 323 | 117.39 |
-76 | 0.10363 | 0.21901 | 24 | 29.847 | 124 | 2.25 | 224 | 25.02 | 324 | 118.94 |
-75 | 0.12127 | 0.25391 | 25 | 31.6874 | 125 | 2.32 | 225 | 25.49 | 325 | 120.51 |
-74 | 0.14168 | 0.29390 | 26 | 33.6260 | 126 | 2.4 | 226 | 25.98 | 326 | 122.09 |
-73 | 0.16528 | 0.33966 | 27 | 35.6671 | 127 | 2.47 | 227 | 26.46 | 327 | 123.68 |
-72 | 0.19252 | 0.39193 | 28 | 37.8154 | 128 | 2.55 | 228 | 26.96 | 328 | 125.30 |
-71 | 0.22391 | 0.45156 | 29 | 40.0754 | 129 | 2.62 | 229 | 27.46 | 329 | 126.93 |
-70 | 0.26004 | 0.51948 | 30 | 42.452 | 130 | 2.7 | 230 | 27.97 | 330 | 128.58 |
-69 | 0.30156 | 0.59672 | 31 | 44.9502 | 131 | 2.78 | 231 | 28.48 | 331 | 130.24 |
-68 | 0.34921 | 0.68446 | 32 | 47.5752 | 132 | 2.87 | 232 | 29.01 | 332 | 131.92 |
-67 | 0.40383 | 0.78397 | 33 | 50.3322 | 133 | 2.95 | 233 | 29.54 | 333 | 133.62 |
-66 | 0.46633 | 0.89668 | 34 | 53.2267 | 134 | 3.04 | 234 | 30.08 | 334 | 135.33 |
-65 | 0.53778 | 1.0242 | 35 | 56.2645 | 135 | 3.13 | 235 | 30.62 | 335 | 137.07 |
-64 | 0.61933 | 1.1682 | 36 | 59.4513 | 136 | 3.22 | 236 | 31.18 | 336 | 138.82 |
-63 | 0.71231 | 1.3306 | 37 | 62.7933 | 137 | 3.32 | 237 | 31.74 | 337 | 140.59 |
-62 | 0.81817 | 1.5136 | 38 | 66.2956 | 138 | 3.42 | 238 | 32.31 | 338 | 142.37 |
-61 | 0.93854 | 1.71950 | 39 | 69.9675 | 139 | 3.51 | 239 | 32.88 | 339 | 144.18 |
-60 | 1.0753 | 1.9509 | 40 | 73.8127 | 140 | 3.62 | 240 | 33.47 | 340 | 146.00 |
-59 | 1.2303 | 2.2106 | 41 | 77.8319 | 141 | 3.72 | 241 | 34.06 | 341 | 147.84 |
-58 | 1.4060 | 2.5018 | 42 | 82.0536 | 142 | 3.82 | 242 | 34.66 | 342 | 149.71 |
-57 | 1.6049 | 2.8277 | 43 | 86.4633 | 143 | 3.93 | 243 | 35.27 | 343 | 151.58 |
-56 | 1.8296 | 3.1922 | 44 | 91.0757 | 144 | 4.04 | 244 | 35.88 | 344 | 153.48 |
-55 | 2.0833 | 3.5993 | 45 | 95.8984 | 145 | 4.16 | 245 | 36.51 | 345 | 155.40 |
-54 | 2.3694 | 4.0535 | 46 | 100.939 | 146 | 4.27 | 246 | 37.14 | 346 | 157.34 |
-53 | 2.6917 | 4.5597 | 47 | 106.206 | 147 | 4.39 | 247 | 37.78 | 347 | 159.30 |
-52 | 3.0542 | 5.1231 | 48 | 111.708 | 148 | 4.51 | 248 | 38.43 | 348 | 161.28 |
-51 | 3.4618 | 5.7496 | 49 | 117.452 | 149 | 4.64 | 249 | 39.09 | 349 | 163.27 |
-50 | 3.9193 | 6.4454 | 50 | 123.4478 | 150 | 4.76 | 250 | 39.76 | 350 | 165.29 |
-49 | 4.4324 | 7.2174 | 51 | 129.7042 | 151 | 4.89 | 251 | 40.44 | 351 | 167.33 |
-48 | 5.0073 | 8.0729 | 52 | 136.2304 | 152 | 5.02 | 252 | 41.12 | 352 | 169.39 |
-47 | 5.6506 | 9.0201 | 53 | 143.0357 | 153 | 5.16 | 253 | 41.81 | 353 | 171.47 |
-46 | 6.3699 | 10.068 | 54 | 150.1298 | 154 | 5.29 | 254 | 42.52 | 354 | 173.58 |
-45 | 7.1732 | 11.225 | 55 | 157.5226 | 155 | 5.43 | 255 | 43.23 | 355 | 175.70 |
-44 | 8.0695 | 12.503 | 56 | 165.2243 | 156 | 5.58 | 256 | 43.95 | 356 | 177.85 |
-43 | 9.0685 | 13.911 | 57 | 173.2451 | 157 | 5.72 | 257 | 44.68 | 357 | 180.02 |
-42 | 10.181 | 15.463 | 58 | 181.5959 | 158 | 5.87 | 258 | 45.42 | 358 | 182.21 |
-41 | 11.419 | 17.17 | 59 | 190.2874 | 159 | 6.03 | 259 | 46.16 | 359 | 184.43 |
-40 | 12.794 | 19.048 | 60 | 199.3309 | 160 | 6.18 | 260 | 46.92 | 360 | 186.66 |
-39 | 14.321 | 21.11 | 61 | 208.7378 | 161 | 6.34 | 261 | 47.69 | 361 | 188.93 |
-38 | 16.016 | 23.372 | 62 | 218.5198 | 162 | 6.50 | 262 | 48.46 | 362 | 191.21 |
-37 | 17.893 | 25.853 | 63 | 228.6888 | 163 | 6.67 | 263 | 49.25 | 363 | 193.52 |
-36 | 19.973 | 28.57 | 64 | 239.2572 | 164 | 6.84 | 264 | 50.05 | 364 | 195.86 |
-35 | 22.273 | 31.544 | 65 | 250.2373 | 165 | 7.01 | 265 | 50.85 | 365 | 198.22 |
-34 | 24.816 | 34.795 | 66 | 261.6421 | 166 | 7.18 | 266 | 51.67 | 366 | 200.61 |
-33 | 27.624 | 38.347 | 67 | 273.4845 | 167 | 7.36 | 267 | 52.49 | 367 | 203.02 |
-32 | 30.723 | 42.225 | 68 | 285.7781 | 168 | 7.55 | 268 | 53.33 | 368 | 205.47 |
-31 | 34.140 | 46.453 | 69 | 298.5363 | 169 | 7.73 | 269 | 54.17 | 369 | 207.93 |
-30 | 37.903 | 51.060 | 70 | 311.7731 | 170 | 7.92 | 270 | 55.03 | 370 | 210.43 |
-29 | 42.046 | 56.077 | 71 | 325.5029 | 171 | 8.11 | 271 | 55.89 | 371 | 212.96 |
-28 | 46.601 | 61.534 | 72 | 339.7401 | 172 | 8.31 | 272 | 56.77 | 372 | 215.53 |
-27 | 51.607 | 67.466 | 73 | 354.4995 | 173 | 8.51 | 273 | 57.66 | 373 | 218.13 |
-26 | 57.104 | 73.909 | 74 | 369.7963 | 174 | 8.72 | 274 | 58.56 | 374 | 220.64 |
-25 | 63.134 | 80.902 | 75 | 385.6459 | 175 | 8.92 | 275 | 59.46 | 374.15 | 221.20 |
-24 | 69.745 | 88.485 | 76 | 402.0641 | 176 | 9.14 | 276 | 60.38 | ||
-23 | 76.987 | 96.701 | 77 | 419.0669 | 177 | 9.35 | 277 | 61.31 | ||
-22 | 84.914 | 105.60 | 78 | 436.6708 | 178 | 9.57 | 278 | 62.25 | ||
-21 | 93.584 | 115.22 | 79 | 454.8923 | 179 | 9.80 | 279 | 63.20 | ||
-20 | 103.06 | 125.63 | 80 | 473.7485 | 180 | 10.03 | 280 | 64.17 | ||
-19 | 113.41 | 136.88 | 81 | 493.2567 | 181 | 10.26 | 281 | 65.14 | ||
-18 | 124.70 | 149.01 | 82 | 513.4345 | 182 | 10.50 | 282 | 66.12 | ||
-17 | 137.02 | 162.11 | 83 | 534.3000 | 183 | 10.74 | 283 | 67.12 | ||
-16 | 150.44 | 176.23 | 84 | 555.8714 | 184 | 10.98 | 284 | 68.13 | ||
-15 | 165.06 | 191.44 | 85 | 578.1673 | 185 | 11.23 | 285 | 69.15 | ||
-14 | 180.97 | 207.81 | 86 | 601.2068 | 186 | 11.49 | 286 | 70.18 | ||
-13 | 198.27 | 225.43 | 87 | 625.009 | 187 | 11.75 | 287 | 71.22 | ||
-12 | 217.07 | 244.37 | 88 | 649.5936 | 188 | 12.01 | 288 | 72.27 | ||
-11 | 237.49 | 264.72 | 89 | 674.9806 | 189 | 12.28 | 289 | 73.34 | ||
-10 | 259.66 | 286.57 | 90 | 701.1904 | 190 | 12.55 | 290 | 74.42 | ||
-9 | 283.69 | 310.02 | 91 | 728.2434 | 191 | 12.83 | 291 | 75.51 | ||
-8 | 309.75 | 335.16 | 92 | 756.1608 | 192 | 13.11 | 292 | 76.61 | ||
-7 | 337.97 | 362.10 | 93 | 784.9639 | 193 | 13.40 | 293 | 77.72 | ||
-6 | 368.52 | 390.95 | 94 | 814.6743 | 194 | 13.69 | 294 | 78.85 | ||
-5 | 401.58 | 421.84 | 95 | 845.3141 | 195 | 13.99 | 295 | 79.99 | ||
-4 | 437.31 | 454.88 | 96 | 876.9057 | 196 | 14.29 | 296 | 81.14 | ||
-3 | 475.92 | 490.19 | 97 | 909.4718 | 197 | 14.60 | 297 | 82.31 | ||
-2 | 517.62 | 527.93 | 98 | 943.0355 | 198 | 14.91 | 298 | 83.48 | ||
-1 | 562.62 | 568.22 | 99 | 977.6203 | 199 | 15.22 | 299 | 84.67 | ||
0 | 611.153 | 611.213 | 100 | 1013.25 | 200 | 15.55 | 300 | 85.88 | ||
Temp. t in °C |
Pi(t) over ice in Pa |
Pw(t) over water in Pa |
Temp. t in °C |
Pw(t) over water in hPa |
Temp. t in °C |
P(t) in bar |
Temp. t in °C |
P(t) in bar |
Temp. t in °C |
P(t) in barbar |
Material is copied in from
[edit] Drucktabellen
Die in der folgenden Tabelle dargestellten Größen sind temperatur- und teilweise auch druckabhängig, richten sich aber in jedem Fall nach dem Aggregatzustand des Wassers (hier s = fest; l = flüssig; g = gasförmig). Dieser wird durch Druck und Temperatur eindeutig bestimmt. Alle Daten wurden Grigull et. al. (1990) entnommen, welche sie nach der Vorgabe durch die "Formulation of the Thermodynamic Properties of Ordinary Water Substance for Scientific and General Use" (1984) der IAPWS mit einer verringerten Iterationsschranke berechneten. Es handelt sich um:
- - die Celsius-Temperatur in Grad Celsius
- v – das spezifische Volumen in Kubikdezimeter je Kilogramm
- h – die spezifische Enthalpie in Kilojoule je Kilogramm
- u – die spezifische Innere Energie in Kilojoule je Kilogramm
- s – die spezifische Entropie in Kilojoule je Kilogramm mal Kelvin
- cp - die spezifische Wärmekapazität bei konstantem Druck in Kilojoule je Kilogramm mal Kelvin
- γ – Volumenausdehnungskoeffzient in 10-3 durch Kelvin
- λ – Wärmeleitfähigkeit in Milliwatt je Meter mal Kelvin
- η – Viskosität in Mikropascal mal Sekunde
- σ – Oberflächenspannung in Millinewton je Meter
[edit] Standardbedingungen
In der folgenden Tabelle handelt es sich um die Stoffdaten bei Standarddruck (SATP), also 0,1 Megapascal (entspricht einem bar). Bis zu einer Temperatur von 99,63 °C, dem Siedepunkt des Wasser bei diesem Druck, liegt das Wasser als Flüssigkeit vor, darüber als Wasserdampf.
°C |
v dm³/kg |
h kJ/kg |
u kJ/kg |
s kJ/(kg·K) |
cp kJ/(kg·K) |
γ 10-3/K |
λ mW / (m·K) |
η μPa·s |
σ1 mN/m |
|
0 | 1,0002 | 0,06 | -0,04 | -0,0001 | 4,228 | -0,080 | 561,0 | 1792 | 75,65 | |
5 | 1,0000 | 21,1 | 21,0 | 0,076 | 4,200 | 0,011 | 570,6 | 1518 | 74,95 | |
10 | 1,0003 | 42,1 | 42,0 | 0,151 | 4,188 | 0,087 | 580,0 | 1306 | 74,22 | |
15 | 1,0009 | 63,0 | 62,9 | 0,224 | 4,184 | 0,152 | 589,4 | 1137 | 73,49 | |
20 | 1,0018 | 83,9 | 83,8 | 0,296 | 4,183 | 0,209 | 598,4 | 1001 | 72,74 | |
25 | 1,0029 | 104,8 | 104,7 | 0,367 | 4,183 | 0,259 | 607,2 | 890,4 | 71,98 | |
30 | 1,0044 | 125,8 | 125,7 | 0,437 | 4,183 | 0,305 | 615,5 | 797,7 | 71,20 | |
35 | 1,0060 | 146,7 | 146,6 | 0,505 | 4,183 | 0,347 | 623,3 | 719,6 | 70,41 | |
40 | 1,0079 | 167,6 | 167,5 | 0,572 | 4,182 | 0,386 | 630,6 | 653,3 | 69,60 | |
45 | 1,0099 | 188,5 | 188,4 | 0,638 | 4,182 | 0,423 | 637,3 | 596,3 | 68,78 | |
50 | 1,0121 | 209,4 | 209,3 | 0,704 | 4,181 | 0,457 | 643,6 | 547,1 | 67,95 | |
60 | 1,0171 | 251,2 | 251,1 | 0,831 | 4,183 | 0,522 | 654,4 | 466,6 | 66,24 | |
70 | 1,0227 | 293,1 | 293,0 | 0,955 | 4,187 | 0,583 | 663,1 | 404,1 | 64,49 | |
80 | 1,0290 | 335,0 | 334,9 | 1,075 | 4,194 | 0,640 | 670,0 | 354,5 | 62,68 | |
90 | 1,0359 | 377,0 | 376,9 | 1,193 | 4,204 | 0,696 | 675,3 | 314,6 | 60,82 | |
99,63 | l | 1,0431 | 417,5 | 417,4 | 1,303 | 4,217 | 0,748 | 679,0 | 283,0 | 58,99 |
g | 1694,3 | 2675 | 2505 | 7,359 | 2,043 | 2,885 | 25,05 | 12,26 | – | |
100 | 1696,1 | 2675 | 2506 | 7,361 | 2,042 | 2,881 | 25,08 | 12,27 | 58,92 | |
200 | 2172,3 | 2874 | 2657 | 7,833 | 1,975 | 2,100 | 33,28 | 16,18 | 37,68 | |
300 | 2638,8 | 3073 | 2810 | 8,215 | 2,013 | 1,761 | 43,42 | 20,29 | 14,37 | |
500 | 3565,5 | 3488 | 3131 | 8,834 | 2,135 | 1,297 | 66,970 | 28,57 | – | |
750 | 4721,0 | 4043 | 3571 | 9,455 | 2,308 | 0,978 | 100,30 | 38,48 | – | |
1000 | 5875,5 | 4642 | 4054 | 9,978 | 2,478 | 0,786 | 136,3 | 47,66 | – | |
1 Die Werte der Oberflächenspannung gelten nicht für den Normaldruck, sondern für den zur jeweiligen Temperatur gehörigen Sättigungsdampfdruck. |
[edit] Tripelpunkt
In der folgenden Tabelle handelt es sich um die Stoffdaten bei einem Druck von 0,0006117 Megapascal (entspricht 0,006117 bar). Bis zu einer Temperatur von 0,01 °C, dem Tripelpunkt des Wassers, liegt das Wasser normalerweise als Eis vor, wurde jedoch hier für unterkühltes Wasser tabelliert. Am Tripelpunkt selbst kann es sowohl als Eis als auch Flüssigkeit oder Wasserdampf vorliegen, bei höheren Temperaturen handelt es sich jedoch wiederum um Wasserdampf.
°C |
v dm³/kg |
h kJ/kg |
u kJ/kg |
s kJ/(kg·K) |
cp kJ/(kg·K) |
γ 10-3/K |
λ mW / (m·K) |
η μPa·s |
σ1 mN/m |
|
0 | 1,0002 | -0,04 | -0,04 | -0,0002 | 4,339 | -0,081 | 561,0 | 1792 | – | |
0,1 | s | 1,0908 | -333,4 | -333,4 | -1,221 | 1,93 | 0,1 | 2,2 | – | – |
l | 1,0002 | 0,0 | 0 | 0 | 4,229 | -0,080 | 561,0 | 1791 | – | |
g | 205986 | 2500 | 2374 | 9,154 | 1,868 | 3,672 | 17,07 | 9,22 | – | |
5 | 209913 | 2509 | 2381 | 9,188 | 1,867 | 3,605 | 17,33 | 9,34 | – | |
10 | 213695 | 2519 | 2388 | 9,222 | 1,867 | 3,540 | 17,60 | 9,46 | – | |
15 | 217477 | 2528 | 2395 | 9,254 | 1,868 | 3,478 | 17,88 | 9,59 | – | |
20 | 221258 | 2537 | 2402 | 9,286 | 1,868 | 3,417 | 18,17 | 9,73 | – | |
25 | 225039 | 2547 | 2409 | 9,318 | 1,869 | 3,359 | 18,47 | 9,87 | – | |
30 | 228819 | 2556 | 2416 | 9,349 | 1,869 | 3,304 | 18,78 | 10,02 | – | |
35 | 232598 | 2565 | 2423 | 9,380 | 1,870 | 3,249 | 19,10 | 10,17 | – | |
40 | 236377 | 2575 | 2430 | 9,410 | 1,871 | 3,197 | 19,43 | 10,32 | – | |
45 | 240155 | 2584 | 2437 | 9,439 | 1,872 | 3,147 | 19,77 | 10,47 | – | |
50 | 243933 | 2593 | 2444 | 9,469 | 1,874 | 3,098 | 20,11 | 10,63 | – | |
60 | 251489 | 2612 | 2459 | 9,526 | 1,876 | 3,004 | 20,82 | 10,96 | – | |
70 | 259043 | 2631 | 2473 | 9,581 | 1,880 | 2,916 | 21,56 | 11,29 | – | |
80 | 266597 | 2650 | 2487 | 9,635 | 1,883 | 2,833 | 22,31 | 11,64 | – | |
90 | 274150 | 2669 | 2501 | 9,688 | 1,887 | 2,755 | 23,10 | 11,99 | – | |
100 | 281703 | 2688 | 2515 | 9,739 | 1,891 | 2,681 | 23,90 | 12,53 | – | |
200 | 357216 | 2879 | 2661 | 10,194 | 1,940 | 2,114 | 32,89 | 16,21 | – | |
300 | 432721 | 3076 | 2811 | 10,571 | 2,000 | 1,745 | 43,26 | 20,30 | – | |
500 | 583725 | 3489 | 3132 | 11,188 | 2,131 | 1,293 | 66,90 | 28,57 | – | |
750 | 772477 | 4043 | 3571 | 11,808 | 2,307 | 0,977 | 100,20 | 38,47 | – | |
1000 | 961227 | 4642 | 4054 | 12,331 | 2,478 | 0,785 | 136,30 | 47,66 | – | |
1 Die Werte der Oberflächenspannung sind hier identisch zur ersten Tabelle, wobei in gleicherweise der Sättigungsdampfdruck angewendet werden muss. |
[edit] Sättigungsdampfdruck
Folgende Tabelle basiert auf verschiedenen, sich gegenseitig ergänzenden Quellen bzw. Näherungsformeln, was jedoch auch nach sich zieht, dass die Werte von unterschiedlicher Güte und Genauigkeit sind. Die Werte des Temperaturbereichs von -100 °C bis 100 °C wurden aus D. Sonntag (1982) entnommen und sind daher recht einheitlich und genau, wenn auch nicht auf dem neuesten Stand. Die Werte des Temperaturbereichs vom Siedepunkt des Wassers bis zum kritischen Punkt, also von 100 °C bis 374 °C, stammen jedoch aus unterschiedlichen Quellen und sind daher wesentlich ungenauer, folglich sollten sie auch nur als Orientierungswerte verstanden und genutzt werden.
Zur richtigen Nutzung der Werte sind folgende Punkte zu beachten:
- Die Werte gelten nur für ebene Oberflächen und in der Abwesenheit anderer Gase bzw. Gasgemische wie Luft. Sie gelten also lediglich für reine Phasen und benötigen einen Korrekturfaktor bei der Anwesenheit von Luft.
- Die Werte wurden nicht nach der Magnus-Formel berechnet, sondern nach etwas genaueren Formeln (siehe unten), mit deren Hilfe sich auch weitere Werte in den entsprechenden Temperaturintervallen berechnen lassen.
- Die Sättigungsdampfdrücke über Wasser im Temperaturintervall von -100 °C bis -50 °C wurden lediglich extrapoliert.
- Die Werte haben unterschiedliche Einheiten (Pa, hPa oder bar), was es beim ablesen zu beachten gilt.
[edit] Formeln
Berechnet wurden die Tabellenwerte von -100 °C bis 100 °C durch folgende Formeln:
Über Wasser:
Temperaturintervall:
- , entspricht
Über Eis:
Temperaturintervall:
- , entspricht
Werden die Temperaturen in Kelvin eingesetzt, so ergibt sich der jeweilige Sättigungsdampfdruck E(T) in Pa.
[edit] Tripelpunkt
Ein wichtiger Grundwert, der nicht in die Tabelle eingetragen wurde, ist der Sättigungsdampfdruck beim Tripelpunkt des Wassers. Der international akzeptierte Bestwert nach Messungen von Guildner, Johnson und Jones (1976) beträgt:
[edit] Tabelle
Temperatur t in °C |
Ei(t) über Eis p in Pa |
Ew(t) über Wasser p in Pa |
Temperatur t in °C |
E(t) über Wasser p in hPa |
Temperatur t in °C |
E(t) p in bar |
Temperatur t in °C |
E(t) p in bar |
Temperatur t in °C |
E(t) p in bar |
---|---|---|---|---|---|---|---|---|---|---|
-100 | 0,0013957 | 0,0036309 | 0 | 6,11213 | 100 | 1,01 | 200 | 15,55 | 300 | 85,88 |
-99 | 0,0017094 | 0,0044121 | 1 | 6,57069 | 101 | 1,05 | 201 | 15,88 | 301 | 87,09 |
-98 | 0,0020889 | 0,0053487 | 2 | 7,05949 | 102 | 1,09 | 202 | 16,21 | 302 | 88,32 |
-97 | 0,002547 | 0,0064692 | 3 | 7,58023 | 103 | 1,13 | 203 | 16,55 | 303 | 89,57 |
-96 | 0,0030987 | 0,0078067 | 4 | 8,13467 | 104 | 1,17 | 204 | 16,89 | 304 | 90,82 |
-95 | 0,0037617 | 0,0093996 | 5 | 8,72469 | 105 | 1,21 | 205 | 17,24 | 305 | 92,09 |
-94 | 0,0045569 | 0,011293 | 6 | 9,35222 | 106 | 1,25 | 206 | 17,6 | 306 | 93,38 |
-93 | 0,0055087 | 0,013538 | 7 | 10,0193 | 107 | 1,3 | 207 | 17,96 | 307 | 94,67 |
-92 | 0,0066455 | 0,016195 | 8 | 10,728 | 108 | 1,34 | 208 | 18,32 | 308 | 95,98 |
-91 | 0,0080008 | 0,019333 | 9 | 11,4806 | 109 | 1,39 | 209 | 18,7 | 309 | 97,31 |
-90 | 0,0096132 | 0,023031 | 10 | 12,2794 | 110 | 1,43 | 210 | 19,07 | 310 | 98,65 |
-89 | 0,011528 | 0,027381 | 11 | 13,1267 | 111 | 1,48 | 211 | 19,46 | 311 | 100 |
-88 | 0,013797 | 0,032489 | 12 | 14,0251 | 112 | 1,53 | 212 | 19,85 | 312 | 101,37 |
-87 | 0,016482 | 0,038474 | 13 | 14,9772 | 113 | 1,58 | 213 | 20,25 | 313 | 102,75 |
-86 | 0,019653 | 0,045473 | 14 | 15,9856 | 114 | 1,64 | 214 | 20,65 | 314 | 104,15 |
-85 | 0,02339 | 0,053645 | 15 | 17,0532 | 115 | 1,69 | 215 | 21,06 | 315 | 105,56 |
-84 | 0,027788 | 0,063166 | 16 | 18,1829 | 116 | 1,75 | 216 | 21,47 | 316 | 106,98 |
-83 | 0,032954 | 0,074241 | 17 | 19,3778 | 117 | 1,81 | 217 | 21,89 | 317 | 108,43 |
-82 | 0,039011 | 0,087101 | 18 | 20,6409 | 118 | 1,86 | 218 | 22,32 | 318 | 109,88 |
-81 | 0,046102 | 0,10201 | 19 | 21,9757 | 119 | 1,93 | 219 | 22,75 | 319 | 111,35 |
-80 | 0,054388 | 0,11925 | 20 | 23,3854 | 120 | 1,99 | 220 | 23,19 | 320 | 112,84 |
-79 | 0,064057 | 0,13918 | 21 | 24,8737 | 121 | 2,05 | 221 | 23,64 | 321 | 114,34 |
-78 | 0,07532 | 0,16215 | 22 | 26,4442 | 122 | 2,12 | 222 | 24,09 | 322 | 115,86 |
-77 | 0,088419 | 0,1886 | 23 | 28,1006 | 123 | 2,18 | 223 | 24,55 | 323 | 117,39 |
-76 | 0,10363 | 0,21901 | 24 | 29,847 | 124 | 2,25 | 224 | 25,02 | 324 | 118,94 |
-75 | 0,12127 | 0,25391 | 25 | 31,6874 | 125 | 2,32 | 225 | 25,49 | 325 | 120,51 |
-74 | 0,14168 | 0,2939 | 26 | 33,626 | 126 | 2,4 | 226 | 25,98 | 326 | 122,09 |
-73 | 0,16528 | 0,33966 | 27 | 35,6671 | 127 | 2,47 | 227 | 26,46 | 327 | 123,68 |
-72 | 0,19252 | 0,39193 | 28 | 37,8154 | 128 | 2,55 | 228 | 26,96 | 328 | 125,3 |
-71 | 0,22391 | 0,45156 | 29 | 40,0754 | 129 | 2,62 | 229 | 27,46 | 329 | 126,93 |
-70 | 0,26004 | 0,51948 | 30 | 42,452 | 130 | 2,7 | 230 | 27,97 | 330 | 128,58 |
-69 | 0,30156 | 0,59672 | 31 | 44,9502 | 131 | 2,78 | 231 | 28,48 | 331 | 130,24 |
-68 | 0,34921 | 0,68446 | 32 | 47,5752 | 132 | 2,87 | 232 | 29,01 | 332 | 131,92 |
-67 | 0,40383 | 0,78397 | 33 | 50,3322 | 133 | 2,95 | 233 | 29,54 | 333 | 133,62 |
-66 | 0,46633 | 0,89668 | 34 | 53,2267 | 134 | 3,04 | 234 | 30,08 | 334 | 135,33 |
-65 | 0,53778 | 1,0242 | 35 | 56,2645 | 135 | 3,13 | 235 | 30,62 | 335 | 137,07 |
-64 | 0,61933 | 1,1682 | 36 | 59,4513 | 136 | 3,22 | 236 | 31,18 | 336 | 138,82 |
-63 | 0,71231 | 1,3306 | 37 | 62,7933 | 137 | 3,32 | 237 | 31,74 | 337 | 140,59 |
-62 | 0,81817 | 1,5136 | 38 | 66,2956 | 138 | 3,42 | 238 | 32,31 | 338 | 142,37 |
-61 | 0,93854 | 1,7195 | 39 | 69,9675 | 139 | 3,51 | 239 | 32,88 | 339 | 144,18 |
-60 | 1,0753 | 1,9509 | 40 | 73,8127 | 140 | 3,62 | 240 | 33,47 | 340 | 146 |
-59 | 1,2303 | 2,2106 | 41 | 77,8319 | 141 | 3,72 | 241 | 34,06 | 341 | 147,84 |
-58 | 1,406 | 2,5018 | 42 | 82,0536 | 142 | 3,82 | 242 | 34,66 | 342 | 149,71 |
-57 | 1,6049 | 2,8277 | 43 | 86,4633 | 143 | 3,93 | 243 | 35,27 | 343 | 151,58 |
-56 | 1,8296 | 3,1922 | 44 | 91,0757 | 144 | 4,04 | 244 | 35,88 | 344 | 153,48 |
-55 | 2,0833 | 3,5993 | 45 | 95,8984 | 145 | 4,16 | 245 | 36,51 | 345 | 155,4 |
-54 | 2,3694 | 4,0535 | 46 | 100,939 | 146 | 4,27 | 246 | 37,14 | 346 | 157,34 |
-53 | 2,6917 | 4,5597 | 47 | 106,206 | 147 | 4,39 | 247 | 37,78 | 347 | 159,3 |
-52 | 3,0542 | 5,1231 | 48 | 111,708 | 148 | 4,51 | 248 | 38,43 | 348 | 161,28 |
-51 | 3,4618 | 5,7496 | 49 | 117,452 | 149 | 4,64 | 249 | 39,09 | 349 | 163,27 |
-50 | 3,9193 | 6,4454 | 50 | 123,4478 | 150 | 4,76 | 250 | 39,76 | 350 | 165,29 |
-49 | 4,4324 | 7,2174 | 51 | 129,7042 | 151 | 4,89 | 251 | 40,44 | 351 | 167,33 |
-48 | 5,0073 | 8,0729 | 52 | 136,2304 | 152 | 5,02 | 252 | 41,12 | 352 | 169,39 |
-47 | 5,6506 | 9,0201 | 53 | 143,0357 | 153 | 5,16 | 253 | 41,81 | 353 | 171,47 |
-46 | 6,3699 | 10,068 | 54 | 150,1298 | 154 | 5,29 | 254 | 42,52 | 354 | 173,58 |
-45 | 7,1732 | 11,225 | 55 | 157,5226 | 155 | 5,43 | 255 | 43,23 | 355 | 175,7 |
-44 | 8,0695 | 12,503 | 56 | 165,2243 | 156 | 5,58 | 256 | 43,95 | 356 | 177,85 |
-43 | 9,0685 | 13,911 | 57 | 173,2451 | 157 | 5,72 | 257 | 44,68 | 357 | 180,02 |
-42 | 10,181 | 15,463 | 58 | 181,5959 | 158 | 5,87 | 258 | 45,42 | 358 | 182,21 |
-41 | 11,419 | 17,17 | 59 | 190,2874 | 159 | 6,03 | 259 | 46,16 | 359 | 184,43 |
-40 | 12,794 | 19,048 | 60 | 199,3309 | 160 | 6,18 | 260 | 46,92 | 360 | 186,66 |
-39 | 14,321 | 21,11 | 61 | 208,7378 | 161 | 6,34 | 261 | 47,69 | 361 | 188,93 |
-38 | 16,016 | 23,372 | 62 | 218,5198 | 162 | 6,5 | 262 | 48,46 | 362 | 191,21 |
-37 | 17,893 | 25,853 | 63 | 228,6888 | 163 | 6,67 | 263 | 49,25 | 363 | 193,52 |
-36 | 19,973 | 28,57 | 64 | 239,2572 | 164 | 6,84 | 264 | 50,05 | 364 | 195,86 |
-35 | 22,273 | 31,544 | 65 | 250,2373 | 165 | 7,01 | 265 | 50,85 | 365 | 198,22 |
-34 | 24,816 | 34,795 | 66 | 261,6421 | 166 | 7,18 | 266 | 51,67 | 366 | 200,61 |
-33 | 27,624 | 38,347 | 67 | 273,4845 | 167 | 7,36 | 267 | 52,49 | 367 | 203,02 |
-32 | 30,723 | 42,225 | 68 | 285,7781 | 168 | 7,55 | 268 | 53,33 | 368 | 205,47 |
-31 | 34,14 | 46,453 | 69 | 298,5363 | 169 | 7,73 | 269 | 54,17 | 369 | 207,93 |
-30 | 37,903 | 51,06 | 70 | 311,7731 | 170 | 7,92 | 270 | 55,03 | 370 | 210,43 |
-29 | 42,046 | 56,077 | 71 | 325,5029 | 171 | 8,11 | 271 | 55,89 | 371 | 212,96 |
-28 | 46,601 | 61,534 | 72 | 339,7401 | 172 | 8,31 | 272 | 56,77 | 372 | 215,53 |
-27 | 51,607 | 67,466 | 73 | 354,4995 | 173 | 8,51 | 273 | 57,66 | 373 | 218,13 |
-26 | 57,104 | 73,909 | 74 | 369,7963 | 174 | 8,72 | 274 | 58,56 | 374 | 220,64 |
-25 | 63,134 | 80,902 | 75 | 385,6459 | 175 | 8,92 | 275 | 59,46 | 374,15 | 221,2 |
-24 | 69,745 | 88,485 | 76 | 402,0641 | 176 | 9,14 | 276 | 60,38 | ||
-23 | 76,987 | 96,701 | 77 | 419,0669 | 177 | 9,35 | 277 | 61,31 | ||
-22 | 84,914 | 105,6 | 78 | 436,6708 | 178 | 9,57 | 278 | 62,25 | ||
-21 | 93,584 | 115,22 | 79 | 454,8923 | 179 | 9,8 | 279 | 63,2 | ||
-20 | 103,06 | 125,63 | 80 | 473,7485 | 180 | 10,03 | 280 | 64,17 | ||
-19 | 113,41 | 136,88 | 81 | 493,2567 | 181 | 10,26 | 281 | 65,14 | ||
-18 | 124,7 | 149,01 | 82 | 513,4345 | 182 | 10,5 | 282 | 66,12 | ||
-17 | 137,02 | 162,11 | 83 | 534,3 | 183 | 10,74 | 283 | 67,12 | ||
-16 | 150,44 | 176,23 | 84 | 555,8714 | 184 | 10,98 | 284 | 68,13 | ||
-15 | 165,06 | 191,44 | 85 | 578,1673 | 185 | 11,23 | 285 | 69,15 | ||
-14 | 180,97 | 207,81 | 86 | 601,2068 | 186 | 11,49 | 286 | 70,18 | ||
-13 | 198,27 | 225,43 | 87 | 625,009 | 187 | 11,75 | 287 | 71,22 | ||
-12 | 217,07 | 244,37 | 88 | 649,5936 | 188 | 12,01 | 288 | 72,27 | ||
-11 | 237,49 | 264,72 | 89 | 674,9806 | 189 | 12,28 | 289 | 73,34 | ||
-10 | 259,66 | 286,57 | 90 | 701,1904 | 190 | 12,55 | 290 | 74,42 | ||
-9 | 283,69 | 310,02 | 91 | 728,2434 | 191 | 12,83 | 291 | 75,51 | ||
-8 | 309,75 | 335,16 | 92 | 756,1608 | 192 | 13,11 | 292 | 76,61 | ||
-7 | 337,97 | 362,1 | 93 | 784,9639 | 193 | 13,4 | 293 | 77,72 | ||
-6 | 368,52 | 390,95 | 94 | 814,6743 | 194 | 13,69 | 294 | 78,85 | ||
-5 | 401,58 | 421,84 | 95 | 845,3141 | 195 | 13,99 | 295 | 79,99 | ||
-4 | 437,31 | 454,88 | 96 | 876,9057 | 196 | 14,29 | 296 | 81,14 | ||
-3 | 475,92 | 490,19 | 97 | 909,4718 | 197 | 14,6 | 297 | 82,31 | ||
-2 | 517,62 | 527,93 | 98 | 943,0355 | 198 | 14,91 | 298 | 83,48 | ||
-1 | 562,62 | 568,22 | 99 | 977,6203 | 199 | 15,22 | 299 | 84,67 | ||
0 | 611,153 | 611,213 | 100 | 1013,25 | 200 | 15,55 | 300 | 85,88 |
[edit] Literatur
- L.A. Guildner, D.P. Johnson und F.E. Jones (1976): Vapor pressure of Water at Its Triple Point. J. Res. NBS - A, Vol. 80A, No. 3, p. 505 - 521
- Klaus Scheffler (1981): Wasserdampftafeln: thermodynam. Eigenschaften von Wasser u. Wasserdampf bis 800°C u. 800 bar (Water Vapor Tables: Thermodynamic Characteristics of Water and Water Vapor to 800°C and 800 bar), Berlin [u.a.] ISBN 3540109307
- D. Sonntag und D. Heinze (1982): Sättigungsdampfdruck- und Sättigungsdampfdichtetafeln für Wasser und Eis. (Saturated Vapor Pressure and Saturated Vapor Density Tables for Water and Ice)(1. Aufl.), VEB Deutscher Verlag für Grundstoffindustrie
- Ulrich Grigull, Johannes Staub, Peter Schiebener (1990): Steam Tables in SI-Units - Wasserdampftafeln. Springer-Verlagdima gmbh
[edit] Notes
- ^ Perman, Jour. Chem. Soc. 83 1168 (1903)
- ^ White, Frank M.: Fluid Mechanics 4th ed. McGraw Hill
- ^ Lange's Handbook of Chemistry, 10th ed. page 1524
- ^ White, Frank M.: Fluid Mechanics 4th ed. McGraw Hill
- ^ Lange's Handbook of Chemistry, 10th ed. page 1524
- ^ L.A. Guildner, D.P. Johnson und F.E. Jones (1976): Vapor pressure of Water at Its Triple Point. J. Res. NBS - A, Vol. 80A, No. 3, p. 505 - 521
- ^
- ^ D. Sonntag und D. Heinze (1982): Sättigungsdampfdruck- und Sättigungsdampfdichtetafeln für Wasser und Eis. (Saturated Vapor Pressure and Saturated Vapor Density Tables for Water and Ice)(1. Aufl.), VEB Deutscher Verlag für Grundstoffindustrie
- ^ Ulrich Grigull, Johannes Staub, Peter Schiebener (1990): Steam Tables in SI-Units - Wasserdampftafeln. Springer-Verlagdima gmbh