Geodesic polyarene

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A geodesic polyarene in organic chemistry is a polycyclic aromatic hydrocarbon with curved convex or concave surfaces [1]. Examples are fullerenes, nanotubes, corannulenes, helicenes and sumanene. The carbon atoms in these systems are to some extent pyramidalized resulting a different pi electron density on either side of the molecule with consequences for reactivity.

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  1. ^ Geodesic polyarenes with exposed concave surfaces Lawrence T. Scott,† Hindy E. Bronstein, Dorin V. Preda, Ronald B. M. Ansems, Matthew S. Bratcher and Stefan Hagen Pure & Appl. Chem., Vol. 71, No. 2, pp. 209–219, 1999 Link