Flame test
From Wikipedia, the free encyclopedia
The flame test is a procedure used in chemistry to detect the presence of certain metal ions. It involves introducing a sample to a flame, and observing the colour that results. The test is based on the fact that each element has its own characteristic emission spectrum. Samples are often held on the looped end of a clean, nonreactive wire or on the tip of a wood stirring stick soaked in water.
Sodium is a common component or contaminant in many compounds and its spectrum tends to dominate over others. The test flame is often viewed through cobalt blue glass to filter out the yellow of sodium and allow for easier viewing of other metal ions.
The flame test is fast and easy to perform, and does not require any special equipment. However, the range of detected elements is small, and the test relies on the subjective experience of the experimentalist rather than any objective measurements. The test has difficulty detecting small concentrations of some elements, while too strong a result may be produced for certain others, which tends to drown out weaker signals. Finally, the test only gives qualitative information, not quantitative data about the actual proportion of elements in the sample.
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[edit] Procedure
- Use a wire loop, usually made of platinum or Nichrome. However any inert object will suffice.
- If the wire loop has been previously used for a flame test, it must be cleaned. Dip it into concentrated hydrochloric acid and then hold it in a non-luminous flame until no discolouration of the flame can be observed.
- Rinse the wire loop in distilled or deionized water.
- Dip the clean loop into an ionic salt or solution and pass it into the non-luminous flame.
- Blue cobalt glass may be desirable to filter sodium's light if sodium ions are present in the solution.
[edit] Common Metals
Some common metals and corresponding colors are:
| Symbol | Name | Color |
|---|---|---|
| As | Arsenic | Blue |
| B | Boron | Bright Green |
| Ba | Barium | Light green |
| Ca | Calcium | Red-orange |
| Cs | Caesium | Pale violet |
| Cu(I) | Copper(I) | Pure Blue |
| Cu(II) | Copper(II) (non-halide) | Emerald green |
| Cu(II) | Copper(II) (halide) | Blue-green (bluish green) |
| In | Indium | Blue |
| Li | Lithium | Crimson |
| K | Potassium | Lilac |
| Mn(II) | Manganese(II) | Yellowish green |
| Mo | Molybdenum | Yellowish green |
| Na | Sodium | Intense yellow |
| P | Phosphorus | Pale bluish green |
| Pb | Lead | Pale green |
| Rb | Rubidium | Pale violet |
| Sb | Antimony | Pale green |
| Se | Selenium | Azure blue |
| Sr | Strontium | Crimson |
| Te | Tellurium | Pale green |
| Tl | Thallium | Pure green |
| Zn | Zinc | Bluish green |
 Gas flame |
 Gas flame seen through cobalt glass |
 Flame test on copper sulphate |
 Flame test on copper sulphate seen through cobalt glass |
 Flame test on sodium carbonate |
 Flame test on sodium carbonate seen through cobalt glass |
[edit] See also
- The Borax bead test is a similar, though more complicated test
- The flame test is also the predecessor of Flame Atomic Absorption Spectrometer.
[edit] External links
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Wikimedia Commons has media related to: |
- Flame Test - Colouring Fire - Pictures of Several Flame Tests, Includes Instructions
- WebMineral.com - Flame Coloration by Element
- All Info About Chemistry - How to Do Flame Tests
