Calcium hydride

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Calcium hydride
Image:Calcium hydride.jpg
General
Systematic name Calcium(II) hydride
Other names Calcium hydride, Calcium dihydride
Molecular formula CaH2
Molar mass 42.094 g/mol
Appearance grey or white-grey powdery solid
Crystal Structure orthorhombic
CAS number [7789-78-8]
Properties
Density and phase 1.7 g/cm3
Solubility in water
Melting point 1000 °C
Boiling point
Heat of fusion 159.2 J/g
Except where noted otherwise, data are given for
materials in their standard state (at 25 °C, 100 kPa)
Infobox disclaimer and references

Calcium hydride is a very reactive solid under normal conditions. It is a grey powdery solid (if obtained commercially) and may spontaneously ignite if not kept out from air. It reacts vigorously with water liberating hydrogen gas, which usually ignites due to the large amount of heat produced:

CaH2 (s) + 2H2O (l) → Ca(OH)2 + 2H2 (g)

This reaction can be quite vigorous. However, with a bit of care, calcium hydride can be used as a desiccant to remove traces of water from organic solvents.

It is used as a powerful reducing agent and for the laboratory preparation of hydrogen gas.

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