Briggs-Rauscher reaction

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The Briggs-Rauscher reaction is an example of a clock reaction which causes a visible oscillation in colour over a period of serval minutes. The reation is typically started by a mixture of clear, colourless solutions which then osciallates between pale orange, clear, and black, making an excellent visual demonstration for chemistry courses.

The reaction:

IO_3^-\,+\,2H_2O_2\,+\,CH_2(CO_2H)_2\,+\,H^+\rightarrow ICH(CO_2H)_2\,+\,2O_2\,+\,3H_2O

takes place in two stages which occur at different rates determined by the concentration of iodine in the solution.

The reduction of iodine can occur by a radical process which is turned on when I- concentration is low, or by a nonradical process when the I- concentration is high. Both processes reduce iodate to hypoiodous acid. The radical process forms hypoiodous acid at a much faster rate than the nonradical process.


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