Bancroft rule

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Bancroft rule says: "The phase in which an emulsifier is more soluble constitutes the continuous phase."

  • In Oil in Water emulsions – emulsifying agents are more soluble in water than in oil (High HLB surfactants).
  • In Water in Oil emulsions – emulsifying agents are more soluble in oil than in water (Low HLB surfactants).
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